Nickel鈥揅obalt Oxide Decorated Three-Dimensional Graphene as an Enzyme Mimic for Glucose and Calcium Detection

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• 作者：Meiyan Wu ; Shangjun Meng ; Qian Wang ; Weili Si ; Wei Huang ; Xiaochen Dong
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2015
• 出版时间：September 30, 2015
• 年：2015
• 卷：7
• 期：38
• 页码：21089-21094
• 全文大小：399K
• ISSN：1944-8252

文摘

Glucose and calcium ion play key roles in human bodies. The needlelike NiCo₂O₄ nanostructures are in situ deposited on three-dimensional graphene foam (3DGF) by a facile hydrothermal procedure. The structure and morphology of the hierarchical NiCo₂O₄/3DGF are characterized by scanning electron microscopy, transmission electron microscopy, and X-ray diffraction. With the self-standing NiCo₂O₄/3DGF as electrochemical electrode, it can realize the high-sensitivity detections for glucose and calcium ion. The limit of detection can reach 0.38 and 4.45 渭M, respectively. In addition, the electrochemical electrode presents excellent selectivity for glucose and calcium ion. This study demonstrates that NiCo₂O₄/3DGF is a unique and promising material for practical application in both glucose and calcium ion sensing.