A Novel Metal-Organic Framework with the Diamondoid Topology Constructed from Pentanuclear Zinc-Carboxylate Clusters
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- 作者：Qian-Rong Fang ; Guang-Shan Zhu ; Zhao Jin ; Ming Xue ; Xiao Wei ; De-Jun Wang ; Shi-Lun Qiu
- 刊名：Crystal Growth & Design
- 出版年：2007
- 出版时间：June 2007
- 年：2007
- 卷：7
- 期：6
- 页码：1035 - 1037
- 全文大小：289K
- 年卷期：v.7,no.6(June 2007)
- ISSN：1528-7505
文摘
A new 3D MOF, [Zn5(
3-O)2(bpdc)4(DMF)2(EtOH)2]·3(DMF)·3(EtOH)·5(H2O) (1) (bpdc = 4,4'-biphenyldicarboxylate,DMF = N,N-dimethylformamide and EtOH = ethanol), has been synthesized under mild conditions. X-ray crystallography reveals thatpolymer 1 consists of a 3D framework with an expanded diamondoid topology constructed from double 4-connected pentanuclear SBUslinked by rigid bpdc ligands. For an unusual pentanuclear framework, polymer 1 shows the favorable CH3OH adsorption behavior andgood optoelectronic effect, which will facilitate the exploration of new types of multifunctional materials.
3-O)2(bpdc)4(DMF)2(EtOH)2]·3(DMF)·3(EtOH)·5(H2O) (1) (bpdc = 4,4'-biphenyldicarboxylate,DMF = N,N-dimethylformamide and EtOH = ethanol), has been synthesized under mild conditions. X-ray crystallography reveals thatpolymer 1 consists of a 3D framework with an expanded diamondoid topology constructed from double 4-connected pentanuclear SBUslinked by rigid bpdc ligands. For an unusual pentanuclear framework, polymer 1 shows the favorable CH3OH adsorption behavior andgood optoelectronic effect, which will facilitate the exploration of new types of multifunctional materials.