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Hard/Soft Heterometallic Network Complex of a Macrocycle with Endo/Exocyclic Coordination
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文摘
One-pot assembly reactions of an S2O4 macrocycle with CuI in the absence and presence of KI afforded an emissive one-dimensional looped coordination polymer linked with a cubane-type copper iodide cluster and an endocoordinated potassium(I) coordination polymer linked with a ribbon-type copper iodide cluster, respectively.

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