A-Site-Doping Enhanced B-Site Ordering and Correlated Magnetic Property in La2鈥?i>xBixCoMnO6

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• 作者：Yijia Bai ; Yanjie Xia ; Hongping Li ; Lin Han ; Zhongchang Wang ; Xiaojie Wu ; Shuhui Lv ; Xiaojuan Liu ; Jian Meng
• 刊名：The Journal of Physical Chemistry C
• 出版年：2012
• 出版时间：August 16, 2012
• 年：2012
• 卷：116
• 期：32
• 页码：16841-16847
• 全文大小：520K
• 年卷期：v.116,no.32(August 16, 2012)
• ISSN：1932-7455

文摘

A series of Bi-doped La_2鈥?i>xBi_xCoMnO₆ double perovskite oxides are synthesized, and the impact of doping on crystal structures and magnetic properties is investigated comprehensively. X-ray photoelectron spectroscopy and Raman spectrum analyses reveal that ordering of Co and Mn ions at B-site is gradually improved with the rise of Bi concentration. Meanwhile, magnetic disordering is suppressed greatly by showing larger magnetic moments. Structurally, the Rietveld refinement shows that the bonds are elongated, while the bond angles are shrunken after doping, giving rise to lowered Curie temperature. We also observe a large negative zero-field-cooling magnetization, which is attributed to the formation of spin antiparallel or canted ferromagnetic domains and clusters that are separated by the antiphase boundaries. First-principles calculations confirm the enhanced Co鈥揗n ordering upon Bi doping by taking into account both the ordering and disordering configurations of La₂CoMnO₆, LaBiCoMnO₆, and Bi₂CoMnO₆. Moreover, we find a spin-state transition in the antisite Co ions from high-spin (Co²⁺-t_2g⁵e_g²) to low-spin state (Co³⁺-t_2g⁶e_g⁰), which is consistent with the increased total magnetic moments by the Bi doping.