Ferrocene-Appended Aryl Triazole for Electrochemical Recognition of Phosphate Ions

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• 作者：Qian-Yong Cao ; Tuhin Pradhan ; Sungtae Kim ; Jong Seung Kim
• 刊名：Organic Letters
• 出版年：2011
• 出版时间：August 19, 2011
• 年：2011
• 卷：13
• 期：16
• 页码：4386-4389
• 全文大小：754K
• 年卷期：v.13,no.16(August 19, 2011)
• ISSN：1523-7052

文摘

A neutral ferrocene-appended aryl triazole receptor 1 for phosphate anions has been synthesized and characterized by X-ray crystal analysis. Among various anions, 1 shows a distinct electrochemical recognition of phosphate anions by its multiple H-bonding (C鈥揌路路路O) with a tetrahedral anion, which is supported by density functional theory based theoretical calculation and ¹H NMR titration results.