Spin-Crossover Cobalt(II) Compound with Banana-Shaped Structure

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• 作者：Shinya Hayami ; Reiko Moriyama ; Yuji Shigeyoshi ; Ryo Kawajiri ; Tadaoki Mitani ; Motoko Akita ; Katsuya Inoue ; and Yonezo Maeda
• 刊名：Inorganic Chemistry
• 出版年：2005
• 出版时间：October 17, 2005
• 年：2005
• 卷：44
• 期：21
• 页码：7295 - 7297
• 全文大小：115K
• 年卷期：v.44,no.21(October 17, 2005)
• ISSN：1520-510X

文摘

A banana-shaped spin-crossover (SCO) cobalt(II) complex[Co(C16-terpy)₂](BPh₄)₂ (1) with long alkyl chains, based on aterpyridine frame, was synthesized. Compound 1 exhibited verygradual SCO behavior and changes in the dielectric constant. Thisshows a way in which SCO materials can be used in electronicdevices.