An Ultra-low-cost Route to Mesostructured TS-1 Zeolite for Efficient Catalytic Conversion of Bulk Molecules

详细信息    查看全文

• 作者：Yalong Ding ; Qingping Ke ; Taotao Liu ; Wenchang Wang ; Mingyang He ; Keqin Yang ; Huile Jin ; Shun Wang ; Tiandi Tang
• 刊名：Industrial & Engineering Chemistry Research
• 出版年：2014
• 出版时间：September 10, 2014
• 年：2014
• 卷：53
• 期：36
• 页码：13903-13909
• 全文大小：386K
• ISSN：1520-5045

文摘

Developing a low-cost route to synthesize mesoporous TS-1 (MTS-1) is of great importance because of its practical application in industry. Herein, we first synthesized a copolymer containing quaternary ammonium groups by a mesoporous template comprising inexpensive starting materials. Subsequently, waterglass (sodium metasilicate), TiCl₃, and copolymer were dispersed in the preformed seeds emulsion, resulting in a gel for synthesizing MTS-1. The counterpart material (CTS-1) was also synthesized by the same procedure except for the absence of the copolymer. Compared with CTS-1, the MTS-1 exhibits good crystallinity and well-defined tetrahedral coordinated Ti species (Ti^IV) in the framework as well as excellent catalytic activity in the oxidation of bulky molecules, such as dibenzothiophene and benzyl phenyl sulfide. This feature may be attributed to the fact that the quaternary ammonium groups on copolymer facilitates the formation of the MFI structure and energetically incorporates the Ti species into the framework.