Essential Role of Viscosity of SWCNT Inks in Homogeneous Conducting Film Formation

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• 作者：Radovan Kukobat ; Takuya Hayashi ; Takafumi Matsuda ; Motoo Sunaga ; Ryusuke Futamura ; Toshio Sakai ; Katsumi Kaneko
• 刊名：Langmuir
• 出版年：2016
• 出版时间：July 12, 2016
• 年：2016
• 卷：32
• 期：27
• 页码：6909-6916
• 全文大小：511K
• 年卷期：0
• ISSN：1520-5827

文摘

Newly developed inorganic single-wall carbon nanotube (SWCNT) inks of the Zn/Al complex and colloidal silica give a quite homogeneous SWCNT film on the polyethylene terephthalate (PET) substrate by the bar-coating method, whereas the surfactant-based SWCNT inks of sodium dodecyl sulfonate (SDS) and sodium dodecyl benzene sulfonate (SDBS) cannot give a homogeneous film. The key properties of SWCNT inks were studied for the production of homogeneous SWCNT films. The contact angle and surface tension of the inorganic dispersant-based SWCNT inks were 70° and 72 mN m^–1, respectively, being close to those of water (71.5° and 71 mN m^–1). The viscosity was significantly higher than that of water (0.90 mPa·s), consequently, providing sufficient wettability, spreadability, and slow drying of the ink on the substrate, leading to homogeneous film formation. On the other hand, the surfactant dispersant-aided SWCNT inks have the contact angle and surface tension twice lower than the inorganic dispersant-based SWCNT inks, guaranteeing better wettability and spreadability than the inorganic dispersant-based inks. However, the small viscosity close to that of water induces a heterogeneous flow of SWCNT ink on rapid drying, leading to inhomogeneous film formation.