Gondola-Shaped Luminescent Tetrarhenium Metallacycles with Crown-Ether-like Multiple Recognition Sites
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- 作者：Malaichamy Sathiyendiran ; Rong-Tang Liao ; P. Thanasekaran ; Tzuoo-Tsair Luo ; N. S. Venkataramanan ; Gene-Hsiang Lee ; Shie-Ming Peng ; Kuang-Lieh Lu
- 刊名：Inorganic Chemistry
- 出版年：2006
- 出版时间：December 11, 2006
- 年：2006
- 卷：45
- 期：25
- 页码：10052 - 10054
- 全文大小：103K
- 年卷期：v.45,no.25(December 11, 2006)
- ISSN：1520-510X
文摘
The self-assembly of gondola-shaped tetrarhenium metallacyclophanes was achieved in near quantitative yield from Re(CO)3corners, a ditopic heterocyclic clip, and a bischelating-bridging unitusing an orthogonal-bonding approach. The highly luminescentmetallacycles contain crown-ether-like recognition sites, which arecapable of selectively recognizing metal ions and planar aromaticmolecules.