Self-Assembly of an Imidazolate-Bridged FeIII/CuII Heterometallic Cage

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• 作者：Florian Reichel ; Jack K. Clegg ; Karsten Gloe ; Kerstin Gloe ; Jan J. Weigand ; Jason K. Reynolds ; Chun-Guang Li ; Janice R. Aldrich-Wright ; Cameron J. Kepert ; Leonard F. Lindoy ; Hong-Chang Yao ; Feng Li
• 刊名：Inorganic Chemistry
• 出版年：2014
• 出版时间：January 21, 2014
• 年：2014
• 卷：53
• 期：2
• 页码：688-690
• 全文大小：221K
• ISSN：1520-510X

文摘

A rare, discrete, mixed-valent, heterometallic Fe(III)/Cu(II) cage, [Cu₆Fe₈L₈](ClO₄)₁₂路蠂solvent (H₃L = tris{[2-{(imidazole-4-yl)methylidene}amino]ethyl}amine), was designed and synthesized via metal-ion-directed self-assembly with neutral tripodal metalloligands. The formation of this coordination cage was demonstrated by X-ray crystallography, ESI mass spectrometry, FT-IR, and UV鈥搗is-NIR spectroscopy.