In Situ-Generated Nano-Gold Plasmon-Enhanced Photoelectrochemical Aptasensing Based on Carboxylated Perylene-Functionalized Graphene

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• 作者：Jing Li ; Wenwen Tu ; Hongbo Li ; Min Han ; Yaqian Lan ; Zhihui Dai ; Jianchun Bao
• 刊名：Analytical Chemistry
• 出版年：2014
• 出版时间：January 21, 2014
• 年：2014
• 卷：86
• 期：2
• 页码：1306-1312
• 全文大小：310K
• ISSN：1520-6882

文摘

A novel in situ-generated nanogold plasmon-enhanced photoelectrochemical aptasensor for Hg²⁺ ions was fabricated using a perylene-3,4,9,10-tetracarboxylic acid/graphene (PTCA-GR) heterojunction. The fabricated photoelectrochemical aptasensor was based on thymine鈥揌g²⁺鈥搕hymine coordination chemistry and the plasmonic near-field absorption enhancement effect of the subsequent specific catalytic formation of nanogold. The energetic electrons from the surface plasmons of the nanogold were injected into the LUMO orbit of the organic PTCA semiconductor and then rapidly transferred to the electrode through GR due to the possible Hg²⁺-DNA molecular wires following irradiation with the visible light (位 > 450 nm) and at a bias voltage of 0.2 V. The fabricated aptasensor was linear in its response to the concentration of Hg²⁺ ions in the range of 5鈥?00 pmol L^鈥?, with a detection limit of 2 pmol L^鈥?. The presence of up to 200-fold greater concentrations of other common metal ions did not interfere with the detection of Hg²⁺ ions in an aqueous system, and the results corresponded well with those obtained by ICP-MS. This novel plasmon-enhanced photoelectrochemical aptasensor exhibited good performance with its high sensitivity, good selectivity, low cost, and portable features. The strategy of the localized surface plasmon resonance through the in situ generation of noble metal nanoparticles paves the way for improvements in PEC aptasensor performance.