Co-Catalyzed Synthesis of 1,4-Dicarbonyl Compounds Using TBHP Oxidant

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• 作者：Feng Zhang ; Peng Du ; Jijun Chen ; Hongxiang Wang ; Qiang Luo ; Xiaobing Wan
• 刊名：Organic Letters
• 出版年：2014
• 出版时间：April 4, 2014
• 年：2014
• 卷：16
• 期：7
• 页码：1932-1935
• 全文大小：310K
• 年卷期：v.16,no.7(April 4, 2014)
• ISSN：1523-7052

文摘

A Co-catalyzed reaction for the construction of 1,4-dicarbonyls has been reported in which cascade organocobalt addition/trapping/Kornblum鈥揇eLaMare rearrangement were involved. In view of the easy availability of starting materials, wide substrate scope, high functionality tolerance, and operational simplicity, this protocol constituted a simple, practical, and powerful alternative compared with previous approaches.