Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via 畏3-Benzylpalladium Intermediates: A New Strategy for Catalytic Dearomatization

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• 作者：Bo Peng ; Sheng Zhang ; Xiaoqiang Yu ; Xiujuan Feng ; Ming Bao
• 刊名：Organic Letters
• 出版年：2011
• 出版时间：October 7, 2011
• 年：2011
• 卷：13
• 期：19
• 页码：5402-5405
• 全文大小：782K
• 年卷期：v.13,no.19(October 7, 2011)
• ISSN：1523-7052

文摘

Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives to produce ortho- or para-substituted carbocycles in satisfactory to excellent yields has been developed. The unprecedented dearomatization reactions proceeded smoothly under mild conditions via 畏³-benzylpalladium intermediates.