Visible-Light-Promoted Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by Rhodium(III) Porphyrins

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• 作者：Mengmeng Yu ; Huize Jing ; Xu Liu ; Xuefeng Fu
• 刊名：Organometallics
• 出版年：2015
• 出版时间：December 28, 2015
• 年：2015
• 卷：34
• 期：24
• 页码：5754-5758
• 全文大小：336K
• ISSN：1520-6041

文摘

Visible-light-promoted hydrolysis of silanes catalyzed by (TAP)Rh–I to produce silanols and dihydrogen efficiently under mild conditions was reported. (TAP)Rh–H was observed as the key intermediate through stoichiometric activation of the Si–H bond by (TAP)Rh–I. Addition of water drove the stoichiometric activation of Si–H into catalysis.