Temperature-Dependent Double Isocyanide Insertion Reaction To Construct a Polycyclic Skeleton

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• 作者：Yaming Tian ; Lumin Tian ; Chunju Li ; Xueshun Jia ; Jian Li
• 刊名：Organic Letters
• 出版年：2016
• 出版时间：February 19, 2016
• 年：2016
• 卷：18
• 期：4
• 页码：840-843
• 全文大小：394K
• ISSN：1523-7052

文摘

A novel strategy to furnish selective double insertion of isocyanides with the aid of potassium tetrachloroaurate(III) has been disclosed. This strategy provides quick access to approach a complex polycyclic skeleton in an efficient manner. Unexpected oxygen migration was also observed when the reaction was conducted at a lower temperature.