One-Pot Synthesis of Benzo[1,4]thiazin-3(4H)-ones and a Theoretical Study of the S鈥揘 Type Smiles Rearrangement Mechanism

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• 作者：Yongmei Zhao ; Yanmiao Wu ; Jiong Jia ; Dongju Zhang ; Chen Ma
• 刊名：The Journal of Organic Chemistry
• 出版年：2012
• 出版时间：October 5, 2012
• 年：2012
• 卷：77
• 期：19
• 页码：8501-8506
• 全文大小：341K
• 年卷期：v.77,no.19(October 5, 2012)
• ISSN：1520-6904

文摘

Benzo[1,4]thiazin-3(4H)-one derivatives are conveniently prepared in one pot via a Smiles rearrangement (SR) tandem reaction. In order to understand the reaction, we present here a theoretical study on the S鈥揘 type SR mechanism.