Total Synthesis of (+)-Sundiversifolide

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• 作者：Hiromasa Yokoe ; Hiroyuki Sasaki ; Tomoyuki Yoshimura ; Mitsuru Shindo ; Masahiro Yoshida ; Kozo Shishido
• 刊名：Organic Letters
• 出版年：2007
• 出版时间：March 15, 2007
• 年：2007
• 卷：9
• 期：6
• 页码：969 - 971
• 全文大小：54K
• 年卷期：v.9,no.6(March 15, 2007)
• ISSN：1523-7052

文摘

The first, enantiocontrolled total synthesis of (+)-sundiversifolide has been accomplished using the sequential ring-closing metathesis, [3,3]-sigmatropic rearrangement, and iodolactonization for the key assembly of the cis-fused oxabicyclo[5.3.0]decene framework of the naturalproduct.