Palladium-Catalyzed C鈥揌 Arylation Using Phosphoramidate as a Directing Group at Room Temperature

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• 作者：Bathoju Chandra Chary ; Sunggak Kim ; Youngchul Park ; Jinsik Kim ; Phil Ho Lee
• 刊名：Organic Letters
• 出版年：2013
• 出版时间：June 7, 2013
• 年：2013
• 卷：15
• 期：11
• 页码：2692-2695
• 全文大小：280K
• 年卷期：v.15,no.11(June 7, 2013)
• ISSN：1523-7052

文摘

This communication describes the first phosphoramidate directing group for synthetically useful arylation. Remarkably, the nature of a new directing group drives selective C鈥揌 bond activation to afford diverse N-aryl phosphoramidates in good to excellent yields at room temperature.