Ti2-Containing 18-Tungsto-2-Arsenate(III) Monolacunary Host and the Incorporation of a Phenylantimony(III) Guest
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- 作者：Kai-Yao Wang ; Zhengguo Lin ; Bassem. S. Bassil ; Xiaolin Xing ; Ali Haider ; Bineta Keita ; Guangjin Zhang ; Cristian Silvestru ; Ulrich Kortz
- 刊名：Inorganic Chemistry
- 出版年：2015
- 出版时间：November 16, 2015
- 年：2015
- 卷：54
- 期：22
- 页码：10530-10532
- 全文大小：256K
- ISSN：1520-510X
文摘
The novel Ti2-containing, sandwich-type 18-tungsto-2-arsenate(III) [(TiIVO)2(伪-AsIIIW9O33)2]14鈥?/sup> (1) was successfully synthesized by the reaction of [TiO]2+ species with [伪-AsIIIW9O33]9鈥?/sup>. The monolacunary polyanion 1 is solution-stable, and a further reaction with 1 equiv of phenylantimony(III) dichloride resulted in [C6H5SbIII(TiIVO)2(伪-AsIIIW9O33)2]12鈥?/sup> (2). Both polyanions 1 and 2 were structurally characterized in the solid state and solution. Electrochemical studies were also performed on both polyanions.
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