BF3·Et2O-Catalyzed Formal [3 + 2] Reaction of Aziridinofullerenes with Carbonyl Compounds

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• 作者：Hai-Tao Yang ; Meng-Lei Xing ; Ye-Fei Zhu ; Xiao-Qiang Sun ; Jiang Cheng ; Chun-Bao Miao ; Fa-Bao Li
• 刊名：Journal of Organic Chemistry
• 出版年：2014
• 出版时间：February 7, 2014
• 年：2014
• 卷：79
• 期：3
• 页码：1487-1492
• 全文大小：324K
• ISSN：1520-6904

文摘

The BF₃路Et₂O-catalyzed formal [3 + 2] reaction of aziridinofullerenes with various carbonyl compounds for the easy preparation of fullerooxazolidines has been developed. Moreover, the reaction of aziridinofullerene with ethyl formate affords the simplest fullerooxazole without substituent.