Copper(I)-Catalyzed Aryl Bromides To Form Intermolecular and Intramolecular Carbon−Oxygen Bonds
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- 作者：Jiajia Niu ; Pengran Guo ; Juntao Kang ; Zhigang Li ; Jingwei Xu ; Shaojing Hu
- 刊名：Journal of Organic Chemistry
- 出版年：2009
- 出版时间：July 17, 2009
- 年：2009
- 卷：74
- 期：14
- 页码：5075-5078
- 全文大小：162K
- 年卷期：v.74,no.14(July 17, 2009)
- ISSN：1520-6904
文摘
A highly efficient Cu-catalyzed C−O bond-forming reaction of alcohol and aryl bromides has been developed. This transformation was realized through the use of copper(I) iodide as a catalyst, 8-hydroxyquinoline as a ligand, and K3PO4 as a base. A variety of functionalized substrates were found to react under these reaction conditions to provide products in good to excellent yields.