Substituent-Enabled Oxidative Dehydrogenative Cross-Coupling of 1,4-Naphthoquinones with Alkenes

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• 作者：Chi Zhang ; Meining Wang ; Zhoulong Fan ; Li-Ping Sun ; Ao Zhang
• 刊名：Journal of Organic Chemistry
• 出版年：2014
• 出版时间：August 15, 2014
• 年：2014
• 卷：79
• 期：16
• 页码：7626-7632
• 全文大小：405K
• ISSN：1520-6904

文摘

A Rh-catalyzed oxidative dehydrogenative cross-coupling of 1,4-naphthquinones with alkenes was achieved by using a substituent-enabled C(sp²)鈥揌 functionalization (SEF) strategy. The method shows high functional group tolerance, broad substrate scope, and great potential for further functional transformations.