Large Heterometallic Dy12Na6 Cage-like Cluster Supported by in Situ Generated Ligand

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• 作者：Guo-Ming Wang ; Jin-Hua Li ; Song-De Han ; Jie Pan ; Li Wei ; Zong-Hua Wang ; Zhen-Zhen Bao
• 刊名：Crystal Growth & Design
• 出版年：2016
• 出版时间：May 4, 2016
• 年：2016
• 卷：16
• 期：5
• 页码：2477-2480
• 全文大小：304K
• 年卷期：0
• ISSN：1528-7505

文摘

A novel heterometallic cluster, Dy₁₂Na₆, has been prepared and characterized. It represents an unprecedented high-nuclearity alkali-metal-Ln cluster with a cage-like shape. In situ generated ligands participated in the formation of the heterometallic cluster. Magnetic measurements suggest that Dy₁₂Na₆ shows slow magnetic relaxation at low temperature.