Self-Assembly of One-Dimensional Nanocrystal Superlattice Chains Mediated by Molecular Clusters
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- 作者：Xianfeng Zhang ; Longfei Lv ; Li Ji ; Guannan Guo ; Limin Liu ; Dandan Han ; Biwei Wang ; Yaqi Tu ; Jianhua Hu ; Dong Yang ; Angang Dong
- 刊名：Journal of the American Chemical Society
- 出版年：2016
- 出版时间：March 16, 2016
- 年：2016
- 卷：138
- 期：10
- 页码：3290-3293
- 全文大小：347K
- ISSN：1520-5126
文摘
Self-assembly of nanocrystal (NC) building blocks into mesoscopic superstructures with well-defined symmetry and geometry is essential for creating new materials with rationally designed properties. Despite the tremendous progress in colloidal assembly, it remains a fundamental challenge to assemble isotropic spherical NCs into one-dimensional (1D) ordered superstructures. Here, we report a new and general methodology that utilizes molecular clusters to induce the anisotropic assembly of NCs in solution, yielding polymer-like, single-NC-wide linear chains comprising as many as ∼1000 close-packed NCs. This cluster-assisted assembly process is applicable to various metallic, semiconductor, and magnetic NCs of different sizes and shapes. Mechanistic investigation reveals that the solvent-induced association of clusters plays a key role in driving the anisotropic assembly of NCs. Our work opens a solution-based route for linearly assembling NCs and represents an important step toward the bottom-up construction of 1D ordered NC superstructures.