Effect of Lanthanum Doping on Ferroelectric and Strain Properties of 0.96Bi1/2(Na0.84K0.16)1/2TiO3-
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- 作者：Vu Diem Ngoc Tran ; Aman Ullah ; Thi Hinh Dinh…
- 关键词：Lead ; free ; piezoelectric ; ferroelectric ; dielectric ; lanthanum
- 刊名：Journal of Electronic Materials
- 出版年：2016
- 出版时间：May 2016
- 年：2016
- 卷：45
- 期：5
- 页码：2639-2643
- 全文大小：1,222 KB
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Aman Ullah (2)
Thi Hinh Dinh (3)
Jae-Shin Lee (3)
1. School of Materials Science and Technology, Hanoi University of Science and Technology, Hanoi, Vietnam
2. Department of Physics, University of Science and Technology, Bannu, Bannu, Khyber Pakhtunkhwa, Pakistan
3. School of Materials Science and Engineering, University of Ulsan, Ulsan, 680-749, Republic of Korea - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Optical and Electronic Materials
Characterization and Evaluation Materials
Electronics, Microelectronics and Instrumentation
Solid State Physics and Spectroscopy - 出版者：Springer Boston
- ISSN：1543-186X
文摘
Lead-free 0.96[Bi1/2(Na0.84K0.16)1/2](1−x)La x TiO3-0.04SrTiO3 (BNKTLax-ST, with x = 0.00, 0.01, 0.02, 0.03, 0.04, and 0.05) ceramics have been synthesized using a conventional solid-state reaction method and their phase transition, dielectric, ferroelectric, and strain properties investigated. X-ray diffraction patterns revealed formation of pure perovskite phase. A phase transition from coexistence of rhombohedral and tetragonal to a pseudocubic phase was observed at x = 0.02. Polarization and bipolar strain hysteresis loops indicated that the ferroelectric order (FE) of BNKT-ST is significantly disrupted by lanthanum doping. The destabilization of the FE order results in degradation of the remanent polarization, coercive field, depolarization temperature (T d), electromechanical coupling factor (k p), and static d 33, accompanied by large electric-field-induced strain of 0.34% at 60 kV/cm with normalized strain of d 33 * = S max/E max = 600 pm/V at a critical composition of around x = 0.02.