Comparative studies on the physical properties of TEOS, TMOS and Na₂SiO₃ based silica aerogels by ambient pressure drying method

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• 作者：Abhijit A. Pisal ; A. Venkateswara Rao
• 关键词：Silica aerogels ; Hydrophobicity ; Thermal conductivity ; Pore size distribution ; Silylation
• 刊名：Journal of Porous Materials
• 出版年：2016
• 出版时间：December 2016
• 年：2016
• 卷：23
• 期：6
• 页码：1547-1556
• 全文大小：1,214 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Characterization and Evaluation Materials
  Physical Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1573-4854
• 卷排序：23

文摘

In order to compare the various precursors of silica aerogels, three different precursors namely TMOS, TEOS and Na₂SiO₃ were studied in this paper. The property differences of the aerogels caused by the three precursors were discussed in terms of reaction process, gelation time, pore size distributions, thermal conductivity, SEM, hydrophobicity and thermal stability. It has been found that the gelation time of the silica gel is strongly dependent on the type of precursor used. During the surface modification process, organic groups were attached to the wet gel skeletons transforming the hydrophilic to the hydrophobic which were characterized by Fourier Transform Infrared spectroscopy (FTIR). It has been found that the contact angle of the Na₂SiO₃ and TMOS precursor based aerogels with water have the higher contact angle of 149° and whereas Na₂SiO₃ precursor based aerogel has the lower contact angle of 130°. The thermal conductivities of the Na₂SiO₃ and TMOS based aerogels have been found to be lower (0.025 and 0.030 W m−1 K−1, respectively) compared to the TEOS based (0.050 W m−1 K−1) aerogels. The pore sizes obtained from the N₂ adsorption measurements varied from 40 to 180, 70 to 190, and 90 to 200 nm for the TEOS, TMOS and Na₂SiO₃ precursor based aerogels, respectively. The scanning electron microscopy studies of the aerogels indicated that the Na₂SiO₃ and TMOS based aerogels show narrow and uniform pores while the particles of SiO₂ network are very small. On the other hand, TEOS aerogel show non-uniform pores such that the numbers of smaller size pores are less compared to the pores of larger size while the SiO₂ particles of the network are larger as compared to both Na₂SiO₃ and TMOS aerogels. Hence, the surface are of the aerogels prepared using TEOS precursor has been found to be the lowest (~620 m2 g−1) compared to the Na₂SiO₃ (~868 m2 g−1) and TMOS (~764 m2 g−1) aerogels.