Self-Assembled Porphyrin Arrays via Zinc¨CNitrogen Coordination

详细信息    查看全文

• 作者：Paul G. Plieger ; Anthony K. Burrell ; Simon B. Hall and David L. Officer
• 关键词：nitrogen coordination ; porphyrin ; self ; assembly ; supramolecular ; zinc
• 刊名：Journal Of Inclusion Phenomena
• 出版年：2005
• 出版时间：2005
• 年：2005
• 卷：53
• 期：3
• 页码：143-148
• 全文大小：306 KB

文摘

A series of alkene linked multiporphyrin zinc complexes have been synthesized and their ability to self-assemble in the presence of either 4,4-bipyridine or DABCO has been investigated. It was found that the sandwich complexes with 4,4-bipyridine proceeded via an intermediary 1:1 complex, whereas the sandwich complexes with DABCO formed discrete complexes. Further additions of an excess of DABCO lead to exchange from within the complex.