Synthesis of s-fac/mer bis(N2-methyldiethylenetriamine, L) nickel(II): X-ray single crystal structures of s-fac[NiL2](NO3)2 and mer[NiL2](CF3CO2)2

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• 作者：Arunendu Mondal ; Inamur R. Laskar ; Nirmalendu Ray Chaudhuri ; Golam Mostafa ; Ashutosh Ghosh and J. Shashidhara Prasad
• 刊名：Transition Metal Chemistry
• 出版年：1999
• 出版时间：1999
• 年：1999
• 卷：24
• 期：3
• 页码：282-286
• 全文大小：125 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1572-901X

文摘

[NiL2](NO3)2 (1) and [NiL2](CF3CO2)2 (2) (L = N2-methyldiethylenetriamine] have been synthesized and their X-ray single crystal structures have been determined. The triamines are ligated to NiII s-facially in (1) and meridionally in (2), with a NiN6 chromophore in each complex.