文摘
GaMnN thin films were deposited on a sapphire (0001) substrate by using laser assisted molecular beam epitaxy. Subsequently, the samples were annealed in the ammonia ambience at 1000?°C for different time lengths. The crystalline quality was improved gradually, and the room temperature ferromagnetism of our samples becomes stronger with the increase of the annealing time within 25?min. The X-ray photoelectron spectra analysis confirmed that the Mn3+ concentration in the GaMnN films increased after annealing. The stronger ferromagnetism was observed in the sample with the higher Mn3+ concentration. However, too long annealing time, such as 35?min, will lead to the degradation of the crystalline quality and the decrease of Mn3+ concentration, which results in the weakened ferromagnetism. The optimal annealing time is 25?min at 1000?°C in our experiments. Finally, the origin of the room temperature ferromagnetism in our samples was discussed preliminarily.