Influence of Magnesium Ion Substitution on Structural and Thermal Behavior of Nanodimensional Hydroxyapatite

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• 作者：Uma Batra (1)
  Seema Kapoor (2)
  Sonia Sharma (2)
  
• 关键词：BET surface area ; hydroxyapatite ; magnesium substitution ; nanopowders ; thermal stability ; β ; tricalcium phosphate
• 刊名：Journal of Materials Engineering and Performance
• 出版年：2013
• 出版时间：June 2013
• 年：2013
• 卷：22
• 期：6
• 页码：1798-1806
• 全文大小：639KB
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• 作者单位：Uma Batra (1)
  Seema Kapoor (2)
  Sonia Sharma (2)
  
  1. Department of Materials & Metallurgical Engineering, PEC University of Technology, Chandigarh, India
  2. University Institute of Chemical Engineering & Technology, Panjab University, Chandigarh, India
  
• ISSN：1544-1024

文摘

Hydroxyapatite (HA), incorporating small amount of magnesium, shows attractive biological performance in terms of improved bone metabolism, osteoblast and osteoclast activity, and bone in-growth. This article reports a systematic investigation on the influence of magnesium (Mg) substitution on structural and thermal behavior of nanodimensional HA. HA and Mg-substituted HA nanopowders were synthesized through sol-gel route. The morphology and size of nanopowders were characterized by transmission electron microscopy. The BET surface area was evaluated from N2 adsorption isotherms. Structural analysis and thermal behavior were investigated by means of Fourier transform infrared spectroscopy, x-ray diffraction, thermogravimetry, and differential thermal analysis. As-synthesized powders consisted of flake-like agglomerates of HA and calcium-deficient HA. The incorporation of magnesium in HA resulted in decrease of crystallite size, crystallinity, and lattice parameters a and c and increase in BET surface area. β-tricalcium phosphate formation occured at lower calcination temperature in Mg-substituted HA than HA.