Simultaneous in situ formation of Ni-based catalysts at the anode for glycerol oxidation and at the cathode for hydrogen evolution
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- 作者：Xiaocai Liang ; Mingshu Xiao ; Minglu Xu ; Dazhang Yang…
- 关键词：Ni ; based catalysts ; Glycerol oxidation ; Hydrogen evolution
- 刊名：Journal of Applied Electrochemistry
- 出版年：2016
- 出版时间：January 2016
- 年：2016
- 卷：46
- 期：1
- 页码：1-8
- 全文大小：1,978 KB
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Mingshu Xiao (1)
Minglu Xu (1)
Dazhang Yang (1)
Yuhua Yan (1)
Yanping Tian (1)
Yuqing Miao (1)
1. University of Shanghai for Science and Technology, Shanghai, 200093, China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Electrochemistry
Physical Chemistry
Industrial Chemistry and Chemical Engineering - 出版者：Springer Netherlands
- ISSN：1572-8838
文摘
This study investigated the simultaneous in situ formation of Ni-based catalysts at the anode and cathode for glycerol oxidation and hydrogen evolution, respectively. The formation of electrocatalysts and their immobilization on the electrode surface occur simultaneously, avoiding the tedious and laborious procedures for the preparation and immobilization of the electrocatalysts. Ni salt in the homogeneous solution was deposited to repair the Ni-based electrocatalysts on the electrode surface, accompanied by the electrolysis of glycerol at the anode and the hydrogen evolution reaction at the cathode, exhibiting good working stability. This technique may find potential applications in the conversion of solar energy into storable fuels via the electrolysis of H2O or small molecules to produce hydrogen.