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Poly(vinyl alcohol)/GO-MMT nanocomposites: Preparation, structure and properties
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  • 作者:Muhammad Raheel (1) (2)
    Kun Yao (1)
    Jiang Gong (1)
    Xue-cheng Chen 闄堝鎴?/a> (1)
    Dong-tao Liu (1)
    Yi-chao Lin (1)
    Dong-mei Cui (1)
    Muhammad Siddiq (2)
    Tao Tang 鍞愭稕 (1)

    1. State Key Laboratory of Polymer Physics and Chemistry
    ; Changchun Institute of Applied Chemistry ; Chinese Academy of Sciences ; Changchun ; 130022 ; China
    2. Department of Chemistry
    ; Quaid-i-Azam University ; Islamabad ; 045320 ; Pakistan
  • 关键词:Clay ; Graphene oxide ; Nanocomposites ; Poly(vinyl alcohol)
  • 刊名:Chinese Journal of Polymer Science
  • 出版年:2015
  • 出版时间:February 2015
  • 年:2015
  • 卷:33
  • 期:2
  • 页码:329-338
  • 全文大小:1,499 KB
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  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Condensed Matter Physics
    Industrial Chemistry and Chemical Engineering
    Polymer Sciences
    Characterization and Evaluation of Materials
  • 出版者:Chinese Chemical Society and Institute of Chemistry, CAS, co-published with Springer
  • ISSN:1439-6203
文摘
A facile, efficient and environment friendly method is established to prepare poly(vinyl alcohol) (PVA) based graphene oxide-montmorillonite (GO-MMT) nanocomposites in aqueous media. GO-MMT nanohybrid is obtained by the combination of GO and MMT in water without any reducing or stabilizing agents. The formation of GO-MMT nanohybrid is due to the hydrogen bonding and crosslinking effects. The sodium ions within MMT sheets act as crosslinkers between GO sheets and MMT platelets. The resultant nanocomposites are characterized by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and mechanical testing. Compared to that of pure PVA, PVA nanocomposites show enhanced thermal stabilities and mechanical properties, which results from strong interfacial adhesion of the nanoadditives in PVA matrix. The further increase in the tensile strength and modulus results from strong interaction between PVA chains and layered GO-MMT as well as good mechanical properties of GO-MMT hybrid, compared to PVA/GO and PVA/MMT nanocompsoites.

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