参考文献:1. Bai X, Ma H, Li X, Dong B, Zheng L (2010) Patterns of gold nanoparticles formed at the air/water interface: effects of capping agents. Langmuir 26:14970鈥?4974. doi:10.1021/la102674f CrossRef 2. Brand谩n SA, D铆az SB, L贸pez Gonz谩lez JJ, Disalvo EA, Ben Altabef A (2007) Experimental and theoretical study of the hydration of phosphate groups in esters of biological interest. Spectrochim Acta A 66:884鈥?97. doi:10.1016/j.saa.2006.05.005 CrossRef 3. Bu W, Zhang L, Hua Z, Chen H, Shi J (2007) Synthesis and characterization of uniform spindle-shaped microarchitectures self-assembled from aligned single-crystalline nanowires of lanthanum phosphates. Cryst Growth Des 7:2305鈥?309. doi:10.1021/cg070104m CrossRef 4. Chen C, Sun L, Li Z, Li L, Zhang J, Zhang Y, Yan C (2010) Ionic liquid-based route to spherical NaYF4 nanoclusters with the assistance of microwave radiation and their multicolor upconversion. Langmuir 26:8797鈥?803. doi:10.1021/la904545a CrossRef 5. Deng YF, Chen J, Zhang DL (2007) Phase diagram data for several salt plus salt aqueous biphasic systems at 298.15聽K. J Chem Eng Data 52:1332鈥?335. doi:10.1021/je7000478 CrossRef 6. Dupont J, de Souza R, Suarez P (2002) Ionic liquid (molten salt) phase organometallic catalysis. Chem Rev 102:3667鈥?691. doi:10.1021/cr010338r CrossRef 7. Hu S, Wang A, Li X, Wang Y, Lowe H (2010) Hydrothermal synthesis of ionic liquid [Bmim]OH-modified TiO2 nanoparticles with enhanced photocatalytic activity under visible light. Chem Asian J 5:1171鈥?177. doi:10.1002/asia.200900629 CrossRef 8. Itoh H, Naka K, Chujo Y (2004) Synthesis of gold nanoparticles modified with ionic liquid based on the imidazolium cation. J Am Chem Soc 126:3026鈥?027. doi:10.1021/ja039895g CrossRef 9. Jia G, Huang YJ, Song YH, Yang M, Zhang LH, You HP (2009) Controllable synthesis and luminescence properties of La(OH)3 and Ln(OH)3:Tb3+ nanocrystals with multiform morphologies. Eur J Inorg Chem 49:3721鈥?726. doi:10.1002/ejic.200900495 CrossRef 10. Le Bideau J, Viau L, Vioux A (2011) Ionogels, ionic liquid based hybrid materials. Chem Soc Rev 40:907鈥?25. doi:10.1039/c0cs00059k CrossRef 11. Liang HB, Zeng Q, Tian ZF, Lin HH, Su Q, Zhang GB, Fu YB (2007) Emission intensities of Tb3+ as a function of x values in Ca5鈭?xTbxNax(PO4)3F phosphor. J Electrochem Soc 154:J177鈥揓180. doi:10.1149/1.2720638 CrossRef 12. Liu K, You HP, Zheng YH, Jia G, Huang YJ, Yang M, Song Y, Zhang LH, Zhang HJ (2010a) Room-temperature synthesis of multi-morphological coordination polymer and tunable white-light emission. Cryst Growth Des 10:16鈥?9. doi:10.1021/cg900990w CrossRef 13. Liu K, You H, Jia G, Zheng Y, Huang Y, Song Y, Yang M, Zhang L, Zhang H (2010b) Hierarchically nanostructured coordination polymer: facile and rapid fabrication and tunable morphologies. Cryst Growth Des 10:790鈥?97. doi:10.1021/cg901170j CrossRef 14. Lorbeer C, Cybinska J, Mudring A (2010) Facile preparation of quantum cutting GdF3:Eu3+ nanoparticles from ionic liquids. Chem Commun 46:571鈥?73. doi:10.1039/b919732j CrossRef 15. Ma Z, Yu J, Dai S (2010) Preparation of inorganic materials using ionic liquids. Adv Mater 22:261鈥?85. doi:10.1002/adma.200900603 CrossRef 16. Murase N, Jagannathan R, Kanematsu Y, Kawasaki Y, Tomita A, Yazawa T, Kushida T (2000) Preparation and fluorescence properties of Eu3+-doped strontium chloroapatite nanocrystals. J Lumin 87鈥?:488鈥?90. doi:10.1016/S0022-2313(99)00219-7 CrossRef 17. Rodriguez-Cabo B, Rodil E, Rodriguez H, Soto A, Arce A (2012) Direct preparation of sulfide semiconductor nanoparitcles from the corresponding bulk powders in an ionic liquid. Angew Chem Int Ed 51:1424鈥?427. doi:10.1002/anie.201106546 CrossRef 18. Roming M, Feldmann C (2008) Selective synthesis of alpha- and beta-SrHPO4 nanoparticles. J Mater Sci 43:5504鈥?507. doi:10.1007/s10853-008-2830-8 CrossRef 19. Sahoo R, Bhattacharya S, Debnath R (2003) A new type of charge compensating mechanism in Ca5(PO4)3F:Eu3+ phosphor. J Solid State Chem 175:218鈥?25. doi:10.1016/S0022-4596(03)00249-4 CrossRef 20. Song YH, You HP, Yang M, Zheng YH, Liu K, Jia G, Huang YJ, Zhang LH, Zhang HJ (2010) Facile synthesis and luminescence of Sr5(PO4)3Cl:Eu2+ nanorod bundles via a hydrothermal route. Inorg Chem 49:1674鈥?678. doi:10.1021/ic902081r CrossRef 21. Song Y, Zou H, Sheng Y, Zheng K, You H (2011) 3D hierarchical architectures of sodium lanthanide sulfates: hydrothermal synthesis, formation mechanisms, and luminescence properties. J Phys Chem C 115:19463鈥?9469. doi:10.1021/jp203903b CrossRef 22. Tang J, Alivisatos AP (2006) Crystal splitting in the growth of Bi2S3. Nano Lett 6:2701鈥?706. doi:10.1021/nl10615930 CrossRef 23. Trpkovska M, 艩optrajanov B, Malkov P (1999) FTIR reinvestigation of the spectra of synthetic brushite and its partially deuterated analogues. J Mol Struct 480鈥?81:661鈥?66. doi:10.1016/S0022-2860(98)00923-5 CrossRef 24. Wan JX, Wang ZH, Chen XY, Mu L, Qian YT (2005) Shape-tailored photoluminescent intensity of red phosphor Y2O3:Eu3+. J Cryst Growth 284:538鈥?43. doi:10.1016/j.jcrysgro.2005.07.040 CrossRef 25. Wang WN, Iskandar F, Okuyama K, Shinomiya Y (2008) Rapid synthesis of non-aggregated fine chloroapatite blue phosphor powders with high quantum efficiency. Adv Mater 20:3422. doi:10.1002/adma.200800415 CrossRef 26. Yang L, Zhu Y, Wang W, Tong H, Ruan M (2006) Synthesis and formation mechanism of nanoneedles and nanorods of manganese oxide octrahedral molecular sieve using an ionic liquid. J Phys Chem B 110:6609鈥?614. doi:10.1021/jp0569739 CrossRef 27. Yang J, Li CX, Cheng ZY, Zhang X, Quan ZW, Zhang CM, Lin J (2007) Size-tailored synthesis and luminescent properties of one-dimensional Gd2O3:Eu3+ nanorods and microrods. J Phys Chem C 111:18148鈥?8154. doi:10.1021/jp0767112 CrossRef 28. Yang M, You HP, Song YH, Huang YJ, Jia G, Liu K, Zheng YH, Zhang LH, Zhang HJ (2009a) Synthesis and lumincescence properties of sheaflike TbPO4 hierarchical architectures with different phase structures. J Phys Chem C 113:20173鈥?0177. doi:10.1021/jp908697t CrossRef 29. Yang M, You HP, Zheng YH, Liu K, Jia G, Song YH, Huang YJ, Zhang LH, Zhang HJ (2009b) Hydrothermal synthesis and luminescent properties of novel ordered sphere CePO4 hierarchical architectures. Inorg Chem 48:11559鈥?1565. doi:10.1021/ic901829v CrossRef 30. Zhang C, Chen J (2010) Facile EG/ionic liquid interfacial synthesis of uniform RE3+ doped NaYF4 nanocubes. Chem Commun 46:592鈥?94. doi:10.1039/b919044a CrossRef 31. Zhang C, Chen J, Zhou Y, Li D (2008) Ionic liquid-based 鈥渁ll-in-one鈥?synthesis and photoluminescence properties of lanthanide fluorides. J Phys Chem C 112:10083鈥?0088. doi:10.1021/jp802083q CrossRef 32. Zhang C, Chen J, Zhu X, Zhou Y, Li D (2009) Synthesis of tributylphosphate capped luminescent rare earth phosphate nanocrystals in an ionic liquid microemulsion. Chem Mater 21:3570鈥?575. doi:10.1021/cm901061c CrossRef 33. Zhang CM, Huang SS, Yang DM, Kang XJ, Shang MM, Peng C, Lin J (2010a) Tunable luminescence in Ce3+, Mn2+-codoped calcium fluorapatite through combining emission and modulation of excitation: a novel strategy to white light emission. J Mater Chem 20:6674鈥?680. doi:10.1039/c0jm01036g CrossRef 34. Zhang X, Zhang J, Huang J, Tang X, Gong M (2010b) Synthesis and luminescence of Eu2+-doped alkaline-earth apatites for application in white LED. J Lumin 130:554鈥?59. doi:10.1016/j.jlumin.2009.10.030 CrossRef 35. Zhao Q, Zheng Y, Guo N, Jia Y, Qiao H, Lv W, You H (2012) 3D-hierarchical Lu2O2S:Eu3+ micro/nano-structures: controlled synthesis and luminescence properties. CrystEngComm 14:6659鈥?664. doi:10.1039/c2ce25631b CrossRef 36. Zhao Q, Guo N, Jia Y, Lv W, Shao B, Jiao M, You H (2013) Facile surfactant-free synthesis and luminescent properties of hierarchical europium-doped lutetium oxide phosphors. J Colloid Interface Sci 394:216鈥?22. doi:10.1016/j.jcis.2012.11.029 CrossRef 37. Zhu R, Yu R, Yao J, Wang D, Ke J (2008) Morphology control of hydroxyapatite through hydrothermal process. J Alloys Compd 457:555鈥?59. doi:10.1016/j.jallcom.2007.03.081 CrossRef
作者单位:Haoyang Zou (1) Yanhua Song (1) Yuefeng Deng (2) Hongguang Zhang (1) Ye Sheng (1) Keyan Zheng (1) Xiuqing Zhou (1) Ji Chen (2)
1. College of Chemistry, Jilin University, Changchun, 130012, People鈥檚 Republic of China 2. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, People鈥檚 Republic of China
ISSN:1572-896X
文摘
Ca5(PO4)3Cl straw-like sheaves and microrods were synthesized via a ionic liquids based hydrothermal method. The ionic liquids [Omim]Cl was utilized to introduce a new chloride source. The influences of the ionic liquids amount and reaction time on the final products were investigated in detail. A possible splitting formation mechanism for the interesting architectures has been proposed to interpret the growth process. The optical properties of the Ca5(PO4)3Cl:Ce3+,Tb3+ phosphor with different morphology have been discussed. This ionic liquids based hydrothermal method is a novel and facile route for the synthesis of other apatite phosphors.