Metal Acetylacetonates as Highly Efficient and Cost Effective Catalysts for the Synthesis of Cyclic Carbonates from CO2 and Epoxides

详细信息    查看全文

• 作者：Subodh Kumar (1)
  Suman L. Jain (1) suman@iip.res.in
  Bir Sain (1) birsain@iip.res.in
• 关键词：Carbon dioxide – ; Epoxide – ; Cyclic carbonate – ; Acetylacetonate – ; Cycloaddition
• 刊名：Catalysis Letters
• 出版年：2012
• 出版时间：May 2012
• 年：2012
• 卷：142
• 期：5
• 页码：615-618
• 全文大小：288.5 KB
• 参考文献：1. Lenton TM (2006) Clim Change 76:7
  2. Serreze MC, Francis JA (2006) Clim Change 76:241
  3. Aresta M (ed) (2010) Carbon dioxide as chemical feedstock. Wiley VCH, Weinheim
  4. Minakata S, Sasaki I, Ide T (2010) Angew Chem Int Ed 49:1309
  5. Leitner W (1996) Coord Chem Rev 155:257
  6. Aresta M (2003) Carbon dioxide recovery utilization. Kluwer Academic Publisher, Dordrecht
  7. Brauden C-I, Schneider G (1994) Carbon dioxide fixation and reduction in biological and model systems. Oxford University Press, Oxford
  8. Sakakura T, Choi J-C, Yasuda H (2007) Chem Rev 107:2365
  9. Darensbourg DJ, Holtcamp MW (1996) Coord Chem Rev 153:155
  10. Fukuoka S, Kawamura M, Komiya K, Tojo M, Hachiya H, Hasegawa K, Aminaka M, Okamoto H, Fukawa I, Konno S (2003) Green Chem 5:497
  11. Biggadike K, Angell RM, Burgess CM, Farrekk RM, Hancick AP, Harker AJ, Irving AJ, Irving WR, Ioannou PA, Procopiou RE, Shaw YE, Solanke OMP, Singh MA, Snowden R, Stubbs S, Walton HE, Weston HE (2000) J Med Chem 43:19
  12. Song J, Zhang Z, Hu S, Wu T, Jiang T, Han B (2009) Green Chem 11:1031
  13. Yamaguchi K, Ebitani K, Yoshida T, Yoshida H, Kaneda K (1999) J Am Chem Soc 121:4526
  14. Lu XB, Zhang YJ, Jin K, Luo LM, Wang H (2004) J Catal 227:537
  15. Mel茅ndez J, North M, Pasquale R (2007) Eur J Inorg Chem 21:3323
  16. Du Y, Cai F, Kong DL, He LN (2005) Green Chem 7:518
  17. He J, Wu T, Zhang Z, Ding K, Han B, Xie Y, Jiang T, Liu Z (2007) Chem Eur J 13:6992
  18. Motokura K, Itagaki S, Iwasawa Y, Miyaji A, Baba T (2009) Green Chem 11:1876
  19. Zhang X, Wang D, Zhao N, Al-Arifi ASN, Aouak T, Al-Othman ZA, Wei W, Sun Y (2009) Catal Commun 11:43
  20. Sun J, Zhang S, Cheng W, Ren J (2008) Tetrahedron Lett 49:3588
  21. Liang S, Liu H, Jiang T, Song J, Yang G, Han B (2011) Chem Commun 47:2131
  22. Lichtenwalter M, Cooper J (1959) U.S. Patent 2873282
  23. Peppel WJ (1958) Ind Eng Chem 50:767
  24. North M, Pasquale R (2009) Angew Chem Int Ed 48:2946
  25. Paddock RL, Nguyen ST (2004) Chem Commun (Camb) 14:1622
  26. Chang T, Jin L, Jing H (2009) ChemCatChem 1:379
  27. Cohen CT, Chu T, Coates GW (2005) J Am Chem Soc 127:10869
  28. Paddock RL, Nguyen ST (2001) J Am Chem Soc 123:11498
  29. Darensbourg DJ, Mackiewicz RM (2005) J Am Chem Soc 127:14026
  30. Decortes A, Castilla AM, Kleij AW (2010) Angew Chem Int Ed 49:9822 and references cited therein
  31. De Pasquale RJ (1973) J Chem Soc Chem Commun 157
  32. Li F, Xia C, Xu L, Sun W, Chen G (2003) Chem Commun 2042
  33. Lu XB, Darensbourg DJ (2012) Chem Soc Rev 41:1462
  34. Huang J-W, Shi M (2003) J Org Chem 68:6705
• 作者单位：1. Chemical Sciences Division, Indian Institute of Petroleum, Council of Scientific and Industrial Research, Dehradun, 248005 India
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Industrial Chemistry and Chemical Engineering
  Pharmacy
  
• 出版者：Springer Netherlands
• ISSN：1572-879X

文摘

Abstract Metal acetylacetonates were found to be efficient and cost effective catalysts for the formation of cyclic carbonates by cycloaddition of carbon dioxide with epoxides, providing high to excellent yields of the corresponding carbonates. Among the various catalysts such as acetylacetonates of Co, Ni, Cu, Zn, Fe, Cr and VO studied, Ni(acac)₂ was found to be promising catalyst for this reaction. The present methodology was found to be superior due to the easy accessibility and comparatively inexpensive nature of metal acetylacetonates than salen complexes.