Chemical and electrochemical grafting of polythiophene onto poly(vinyl chloride): synthesis, characterization, and materials properties
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- 作者：Bakhshali Massoumi ; Amir Farnoudian-Habibi…
- 关键词：Poly(vinyl chloride) ; Conductive polymers ; Polythiophene ; Graft copolymer ; Processability
- 刊名：Journal of Solid State Electrochemistry
- 出版年：2016
- 出版时间：February 2016
- 年：2016
- 卷：20
- 期：2
- 页码：489-497
- 全文大小：1,004 KB
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Amir Farnoudian-Habibi (2)
Mehdi Jaymand (2)
1. Department of Chemistry, Payame Noor University, P.O. BOX: 19395-3697, Tehran, Islamic Republic of Iran
2. Research Center for Pharmaceutical Nanotechnology, Tabriz University of Medical Sciences, P.O. Box: 51656-65811, Tabriz, Islamic Republic of Iran - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Physical Chemistry
Analytical Chemistry
Industrial Chemistry and Chemical Engineering
Characterization and Evaluation Materials
Condensed Matter
Electronic and Computer Engineering - 出版者：Springer Berlin / Heidelberg
- ISSN：1433-0768
文摘
A facile strategy for chemical and electrochemical grafting of polythiophene onto poly(vinyl chloride) (PVC) is reported. For this purpose, a thiophene-functionalized PVC macromonomer (ThPVCM) was synthesized using a Kumada cross-coupling reaction. The synthesis of macromonomer was verified by means of Fourier transform infrared (FTIR) and 1H nuclear magnetic resonance (NMR) spectroscopes. The graft copolymerization of thiophene monomers onto ThPVCM was initiated by oxidized thiophene groups coupled onto PVC backbone after addition of ferric chloride (FeCl3) via oxidation polymerization method. Moreover, the electrochemical graft copolymerization of thiophene onto ThPVCM was performed via constant potential electrolysis in the acetonitrile (ACN)–tetraethylammonium tetrafluoroborate (TEAFB) solvent–electrolyte couple. The PVC-g-PTh obtained was characterized by means of FTIR spectroscopy and gel permeation chromatography (GPC), and its electroactivity behavior was verified under cyclic voltammetric conditions. Moreover, thermal behavior of the synthesized polymer was investigated by means of thermogravimetric analysis (TGA). Keywords Poly(vinyl chloride) Conductive polymers Polythiophene Graft copolymer Processability