Synthesis, flame retardancy, and thermal degradation behaviors of novel organo-phosphorus compounds derived from 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO)

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• 作者：Woojung Kim ; DongQuy Hoang ; Hai Vothi ; Congtranh Nguyen…
• 关键词：9 ; 10 ; dihydro ; 9 ; oxa ; 10 ; phosphaphenanthrene ; 10 ; oxide (DOPO) ; organo ; phosphorus ; flame retardant ; phosphorus content ; acrylonitrile ; butadiene ; styrene copolymer (ABS)
• 刊名：Macromolecular Research
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：24
• 期：1
• 页码：66-73
• 全文大小：595 KB
• 参考文献：(1).C. J. Hilado, Flammability Handbook for Plastics, 5th ed., Technomic Publishing Co., Lancaster, Pennsylvania, 1998.
  (2).J. Troitzsch, Plastics Flammability Handbook, 3rd ed., Hanser Publications, Munich, 2004.CrossRef
  (3).D. Price, G. Anthony, and P. Carty, in Fire Retardant Materials, A. R. Horrocks and D. Price, Eds., Woodhead Publishing Ltd., England, 2001, pp 1–30.
  (4).P. Svec, L. Rosik, Z. Horak, and F. Vecerka, Styrene-Based Plastics and Their Modification, Ellis Horwood, New York, 1990.
  (5).P. Luijk, H. A. J. Govers, G. B. Eijkel, and J. J. Boon, J. Anal. Appl. Pyrolysis, 20, 11 (1991).CrossRef
  (6).R. Dumler and H. Thoma, Chemosphere, 19, 11 (1989).
  (7).Y. Nakamura, M. Yamaguchi, M. Okubo, and T. Matsumoto, J. Appl. Polym. Sci., 45, 11 (1992).
  (8).K. S. Annakurtty and K. Kishore, Polymer, 29, 11 (1988).
  (9).P. Kannan and K. Kishore, Polymer, 33, 11 (1992).CrossRef
  (10).M. Banks, J. R. Ebdon, and M. Johnson, Polymer, 34, 11 (1993).CrossRef
  (11).C. E. Anderson, D. E. Ketchun, and W. P. Mountain, J. Fire Sci., 6, 11 (1998).
  (12).L. Costa, L. R. di Montelera, G. Camino, E. D. Weil, and E. M. Pearce, J. Appl. Polym. Sci., 68, 11 (1998).CrossRef
  (13).S. V. Levchik, Proceedings of the 17th Annual BCC Conference on Recent Advances in Flame Retardancy of Polymeric Materials, Stamford, USA, 2006.
  (14).C. S. Wang, J. Y. Shieh, and Y. M. Sun, J. Appl. Polym. Sci., 70, 11 (1998).
  (15).C. S. Wang and C. H. Lin, Polymer, 40, 11 (1999).
  (16).C. S. Wang and C. H. Lin, J. Appl. Polym. Sci., Part A: Polym. Chem., 37, 11 (1999).CrossRef
  (17).C. S. Wang and J. Y. Shieh, J. Appl. Polym. Sci., 73, 11 (1999).
  (18).J. Y. Shieh and C. S. Wang, Polymer, 42, 11 (2001).
  (19).Y. L. Liu, Polymer, 42, 11 (2001).
  (20).Y. L. Liu, J. Polym. Sci., Part A: Polym. Chem., 40, 11 (2002).
  (21).M. Hussain, R. J. Varley, Z. Mathys, Y. B. Cheng, and G. P. Simon, J. Appl. Polym. Sci., 91, 11 (2004).CrossRef
  (22).Y. L. Liu, W. L. Wei, and W. Y. Chen, Polym. Int., 52, 11 (2003).
  (23).C. H. Lin, Polymer, 45, 11 (2004).
  (24).D. D. Purnanand, P. D. Shakya, and S. Shefalis, Phosphorus Sulfur Silicon Relat. Elem., 177, 11 (2002).CrossRef
  (25).M. J. P. Harger and M. A. Stephen, J. Chem. Soc., Perkin Trans., 1, 11 (1981).
  (26).A. A. Abduvakhabov and S. K. Kasymov, Uzbekskii Khimicheskii Zhurnal, 5, 11 (1983).
  (27).D. Hoang and J. Kim, Macromol. Res., 21, 11 (2013).
  (28).D. Hoang, W. Kim, H. An, and J. Kim, Macromol. Res., 23, 11 (2015).
  (29).A. Lorenzetti, M. Modesti, S. Besco, D. Hrelja, and S. Donadi, Polym. Degrad. Stab., 96, 11 (2011).CrossRef
  (30).U. Braun, A. I. Balabanovich, B. Schartel, U. Knoll, J. Artner, M. Ciesielski, M. Doring, R. Perez, J. K. W. Sandler, V. Altstadt, T. Hoffmann, and D. Pospiech, Polymer, 47, 11 (2006).CrossRef
  (31).D. Price, L. K. Cunliffe, K. J. Bullett, T. R. Hull, G. J. Milnes, J. R. Ebdon, B. J. Hunt, and P. Joseph, Polym. Degrad. Stab., 92, 11 (2007).CrossRef
  (32).A. Schafer, S. Seibold, W. Lohstroh, O. Walter, and M. Doring, J. Appl. Polym. Sci., 105, 11 (2007).CrossRef
  (33).A. Buczko, T. Stelzig, L. Bommer, D. Rentsch, M. Heneczkowski, and S. Gaan, Polym. Degrad. Stab., 107, 11 (2014).CrossRef
  (34).A. Konig and E. Kroke, Fire Mater., 36, 11 (2012).CrossRef
  (35).B. Schartel, A. I. Balabanovich, U. Braun, U. Knoll, J. Artner, M. Ciesielski, M. Doring, R. Perez, J. K. W. Sandler, V. Altstadt, T. Hoffmann, and D. Pospiech, J. Appl. Polym. Sci., 104, 11 (2007).CrossRef
  (36).A. Konig and E. Kroke, Polym. Adv. Technol., 22, 5 (2011).CrossRef
  (37).I. Butnaru, M. P. Fernandez-Ronco, J. Czech-Polak, M. Heneczkowski, M. Bruma, and S. Gaan, Polymers, 7, 11 (2015).CrossRef
  (38).A. Twarowski, Combust. Flame, 102, 11 (1995).CrossRef
  (39).E. J. P. Zegers and E. M. Fisher, Combust. Flame, 115, 11 (1998).CrossRef
  (40).O. P. Korobeinichev, V. M. Shvartsberg, and A. A. Chernov, Combust. Flame, 118, 11 (1999).
  (41).M. A. Macdonald, F. C. Gouldin, and E. M. Fisher, Combust. Flame, 124, 11 (2001).CrossRef
  (42).C. Nguyen and J. Kim, Polym. Adv. Technol., 22, 11 (2011).CrossRef
  (43).D. Hoang and J. Kim, Polym. Degrad. Stab., 93, 11 (2008).
  (44).D. Hoang and J. Kim, Polym. Degrad. Stab., 93, 11 (2008).
  
• 作者单位：Woojung Kim (1)
  DongQuy Hoang (1) (2)
  Hai Vothi (1)
  Congtranh Nguyen (1) (2)
  Thanhkieu Giang (1)
  Haiyan An (1)
  Jinhwan Kim (1)
  
  1. Department of Polymer Science and Engineering, Sungkyunkwan University, Suwon, Gyeonggi, 16419, Korea
  2. University of Science, Vietnam National University, Ho Chi Minh City, Vietnam
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Polymer Sciences
  Characterization and Evaluation of Materials
  Soft and Granular Matter, Complex Fluids and Microfluidics
  Nanochemistry
  Nanotec
  
• 出版者：The Polymer Society of Korea, co-published with Springer
• ISSN：2092-7673

文摘

A series of novel organo-phosphorus compounds was synthesized from 9,10-dihydro-9-oxa-10-phosphaphenanthrene- 10-oxide (DOPO) in an attempt to obtain high phosphorus (P) containing halogen-free flame retardant (FR). The success of synthesis was confirmed by 1H and 31P NMR spectra. The P content of FR varied from 12.95 to 19.22 wt%. Thermal stabilities of synthesized FRs and their flame retardancy for Acrylonitrile-Butadiene- Styrene copolymer (ABS) were investigated by thermal gravimetric analysis (TGA) and the classification of UL-94 V-0 rating, respectively. 27.5-30.0 wt% FR loadings gave the V-0 rating for the ABS/FR mixtures and no fume emission was observed. It was found that the flame retardancy strongly depends on the P content of FR and 5.03-5.30 wt% P is required in the formulation to exhibit self-extinguishing ability when phosphinate or phosphonate FRs are employed. The mode of flame retardancy action is also discussed.