Hydrothermal Synthesis of Lanthanide and Lanthanide-Transition-Metal Cluster Organic Frameworks via Synergistic Coordination Strategy

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• 关键词：Heterometallic compounds ; Hydrothermal synthesis ; Lanthanide cluster organic framework ; Rigid ligands ; Synergistic coordination
• 刊名：Structure & Bonding
• 出版年：2017
• 出版时间：2017
• 年：2017
• 卷：173
• 期：1
• 页码：97-119
• 全文大小：1,981 KB
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• 作者单位：Jian-Wen Cheng (3) (4)
  Guo-Yu Yang (3) (4)
  
  3. MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, Beijing, 100081, China
  4. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang, 321004, China
  
• 丛书名：Recent Development in Clusters of Rare Earths and Actinides: Chemistry and Materials
• ISBN：978-3-662-53303-1
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1616-8550
• 卷排序：173

文摘

The study of polynuclear lanthanide (Ln) complexes has been a field of rapid growth in coordination chemistry. Lanthanide clusters synthesized via a ligand-controlled hydrolytic approach using different flexible α-amino acids have been well summarized. In this chapter, we describe efforts to synthesize lanthanide and lanthanide-transition-metal (Ln-TM) cluster organic frameworks using rigid ligands of isonicotinic acid (HIN), 4-pyridin-4-ylbenzoic acid (HL), nicotinic acid (HNA), and 4-(3-pyridyl)benzoic acid (HL′) under hydrothermal condition. In addition, the synergistic coordination between these rigid ligands with other organic/inorganic ligands has also been discussed.