In situ synthesis of block copolymer nano-assemblies by polymerization-induced self-assembly under heterogeneous condition
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- 作者：Sheng-li Chen ; Peng-fei Shi ; Wang-qing Zhang 张望清
- 关键词：Block copolymers ; Self ; assembly ; Emulsion RAFT polymerization ; Dispersion RAFT polymerization ; Seeded RAFT polymerization
- 刊名：Chinese Journal of Polymer Science
- 出版年：2017
- 出版时间：April 2017
- 年：2017
- 卷：35
- 期：4
- 页码：455-479
- 全文大小：
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Polymer Sciences; Industrial Chemistry/Chemical Engineering; Characterization and Evaluation of Materials; Condensed Matter Physics;
- 出版者：Chinese Chemical Society and Institute of Chemistry, CAS
- ISSN：1439-6203
- 卷排序：35
文摘
Controlled synthesis of amphiphilic block copolymer nanoparticles in a convenient way is an important and interest topic in polymer science. In this review, three formulations of polymerization-induced self-assembly to in situ synthesize block copolymer nanoparticles are briefly introduced, which perform by reversible addition-fragmentation chain transfer (RAFT) polymerization under heterogeneous conditions, e.g., aqueous emulsion RAFT polymerization, dispersion RAFT polymerization and especially the recently proposed seeded RAFT polymerization. The latest developments in several selected areas on the synthesis of block copolymer nano-assemblies are highlighted.