Synthesis and structure of a 2D ?3D framework with coexistence of hydrogen bonds and polythreading character

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• 作者：Ming-Dao Zhang ; Qi-Fan Zhuang ; Jing Xu ; Hui Cao
• 刊名：Crystallography Reports
• 出版年：2015
• 出版时间：December 2015
• 年：2015
• 卷：60
• 期：7
• 页码：1106-1110
• 全文大小：745 KB
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• 作者单位：Ming-Dao Zhang (1) (2)
  Qi-Fan Zhuang (1)
  Jing Xu (1)
  Hui Cao (1)
  
  1. Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Collaborative Innovation Center for Atmospheric Environment & Equipment Technology, School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, 210044, Jiangsu, P. R. China
  2. State Key Laboratory of Coordination Chemistry, Nanjing University, 210093, Beijing, P. R. China
  
• 刊物类别：Physics and Astronomy
• 刊物主题：Physics
  Crystallography
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1562-689X

文摘

The title complex, {[Co(BPPA)(5-OH-bdc)] · (H₂O)} _n was prepared under hydrothermal conditions based on two ligands, namely, bis(4-(pyridin-4-yl)phenyl)amine (BPPA) and 5-hydroxyisophthalic acid (5-OH-H₂ bdc). 5-OH-bdc 2-/sup> anions coordinated to Co atoms to give layers in crystal. BPPA ligands coordinate to Co atoms and thread into the adjacent layers. There are hydrogen bonds between adjacent layers, giving rise to a 2D ?3D framework. The article is published in the original.