The effect of H2O2/Fe2+ catalytic oxidation system on the morphology, structure and properties of flake-like poly(2,3-dimethylaniline)

详细信息    查看全文

• 作者：Jun Yan (1)
  Li Ma (1)
  Mengyu Gan (1)
  Xiao Li (1)
  Zhitao Li (1)
  Jihai Tang (1)
  Ying Tu (1)
  Haifeng Hu (1)
  
• 关键词：poly(2 ; 3 ; dimethylaniline) ; polyaniline ; flake ; hydrogen peroxide ; corrosion protection
• 刊名：Macromolecular Research
• 出版年：2014
• 出版时间：August 2014
• 年：2014
• 卷：22
• 期：8
• 页码：853-858
• 全文大小：543 KB
• 参考文献：1. M. Wan, / Macromol. Rapid Commun., 30, 963 (2009). CrossRef
  2. Y. Hao, B. Zhou, F. Wang, J. Li, L. Deng, and Y. N. Liu, / Biosens. Bioelectron., 52, 422 (2014). CrossRef
  3. S. Banerjee, D. Konwar, and A. Kumar, / Sens. Actuators B: Chem., 190, 199 (2014). CrossRef
  4. C. V. Tuan, M. A. Tuan, N. V. Hieu, and T. Trung, / Curr. Appl. Phys., 12, 1011 (2012). CrossRef
  5. H. Wang, E. Zhu, J. Yang, P. Zhou, D. Sun, and W. Tang, / J. Phys. Chem. C, 116, 13013 (2012). CrossRef
  6. M. Oyharcabal, T. Olinga, M.P. Foulc, S. Lacomme, E. Gontier, and V. Vigneras, / Compos. Sci. Technol., 74, 107 (2013). CrossRef
  7. J. M. Yeh, S. J. Liou, C. Y. Lai, and P. C. Wu, / Chem. Mater., 13, 1131 (2001). CrossRef
  8. L. Ma, D. Fu, M. Gan, F. Zhang, Z. Li, and S. Li, / J. Appl. Polym. Sci., 130, 4528 (2013).
  9. N. Jadhav, C. A. Vetter, and V. J. Gelling, / Electrochim. Acta, 102, 28 (2013). CrossRef
  10. A. Kalendov谩, / Prog. Org. Coat., 46, 324 (2003). CrossRef
  11. M. Siljeg, L. Foglar, and M. Kukucka, / J. Hazard. Mater., 178, 572 (2010). CrossRef
  12. Y. Wang, X. Jing, and J. Kong, / Synth. Met., 157, 269 (2007). CrossRef
  13. H. Zhang, J. Wang, Z. Wang, F. Zhang, and S. Wang, / Macromol. Rapid Commun., 30, 1577 (2009). CrossRef
  14. S. Zhu, X. Chen, Y. Gou, Z. Zhou, M. Jiang, J. Lu, and D. Hui, / Polym. Adv. Technol., 23, 796 (2012). CrossRef
  15. C. Laslau, Z. Zujovic, and J. Travas-Sejdic, / Prog. Polym. Sci., 35, 1403 (2010). CrossRef
  16. L. Ma, C. H. Huang, and M. Gan, / J. Appl. Polym. Sci., 127, 3699 (2013). CrossRef
  17. Y. C. Chung, J. S. Park, C. H. Shin, J. W. Choi, and B. C. Chun, / Macromol. Res., 20, 66 (2012). CrossRef
  18. E. Kim, S. Kim, and C. Lee, / Macromol. Res., 18, 215 (2010). CrossRef
  19. S. Baek, J. J. Ree, and M. Ree, / J. Polym. Sci. Part A: Polym. Chem., 40, 983 (2002). CrossRef
  20. G. Li, C. Zhang, Y. Li, H. Peng, and K. Chen, / Polymer, 51, 1934 (2010). CrossRef
  21. H. D. Tran, I. Norris, J. M. D鈥橝rcy, H. Tsang, Y. Wang, B. R. Mattes, and R. B. Kaner, / Macromolecules, 41, 7405 (2008). CrossRef
  22. X. G. Li, W. Duan, M. R. Huang, and Y. L. Yang, / J. Polym. Sci. Part A: Polym. Chem., 39, 3989 (2001). CrossRef
  23. Q. Tang, X. Sun, Q. Li, J. Wu, J. Lin, and M. Huang, / Mater. Lett., 63, 540 (2009). CrossRef
  24. G. Song, J. Han, J. Bo, and R. Guo, / J. Mater. Sci., 44, 715 (2008). CrossRef
  25. J. Stejskal, I. Sapurina, and M. Trchov谩, / Prog. Polym. Sci., 35, 1420 (2010). CrossRef
  26. H. Wang and Y. Lu, / Synth. Met., 162, 1369 (2012). CrossRef
  27. M. Trchov谩, I. 艩ed臎nkov谩, E. N. Konyushenko, J. Stejskal, P. Holler, and G. 膯iri膰-Marjanovi膰, / J. Phys. Chem. B, 110, 9461 (2006). CrossRef
  28. J. Stejskal, I. Sapurina, M. Trchov谩, E. N. Konyushenko, and P. Holler, / Polymer, 47, 8253 (2006 ). CrossRef
  29. J. E. P. da Silva, D. L. A. de Faria, S. I. C. de Torresi, and M. L. A. Temperini, / Macromolecules, 33, 3077 (2000). CrossRef
  30. W. Lu, R. L. Elsenbaumer, and B. Wessling, / Synth. Met., 71, 2163 (1995). CrossRef
  31. B. Wessling, / Synth. Met., 85, 1313 (1997). CrossRef
  
• 作者单位：Jun Yan (1)
  Li Ma (1)
  Mengyu Gan (1)
  Xiao Li (1)
  Zhitao Li (1)
  Jihai Tang (1)
  Ying Tu (1)
  Haifeng Hu (1)
  
  1. College of Chemistry & Chemical Engineering, Chongqing University, Chongqing, 400030, P. R. China
  
• ISSN：2092-7673

文摘

In this work, flake-like poly(2,3-dimethylaniline) (P(2,3-DMA)) with enhanced thermal stability and anticorrosive ability was synthesized by in situ polymerization using H2O2/Fe2+ catalytic oxidation system, comparing with traditional oxidant ammonium persulfate (APS) synthetic method. The structure and morphology of the samples were characterized Fourier transform infrared (FTIR) spectra, X-ray diffraction (XRD) and field-emission scanning electron microscope (FESEM). The experimental results demonstrated that using H2O2/Fe2+ catalytic oxidation system was more inclined to form the two-dimensional P(2,3-DMA) flakes. The enhancement in thermostability and corrosion resistance was attributed to the formation of phenazine-like structures in the polymer chains, which could serve as templates to form the flake-like morphology. In addition, using H2O2/Fe2+ catalytic oxidation system is more environmental friendly than the APS method that can avoid ammonium pollution on aquatic life as well as waters.