An Unusual Sodium-Ammonia Tetraborate Na1.33(NH4)0.67B4O5(OH)4·(H2O)2 Containing Tetranuclear Sodium

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• 作者：Chun-Yang Pan ; Dong-Yang Wu ; Yuan-Zhang Luo ; Feng-Hua Zhao…
• 关键词：Tetraborate ; Crystal structure ; Solvothermal
• 刊名：Journal of Cluster Science
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：27
• 期：1
• 页码：85-93
• 全文大小：706 KB
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• 作者单位：Chun-Yang Pan (1)
  Dong-Yang Wu (1)
  Yuan-Zhang Luo (1)
  Feng-Hua Zhao (1)
  Hong-Mei Yang (1)
  
  1. School of Light Industry and Chemical Engineering, Guangdong University of technology, Guangzhou, 510002, Guangdong, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Inorganic Chemistry
  Physical Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1572-8862

文摘

A sodium-ammonia tetraborate Na_1.33(NH₄)_0.67B₄O₅(OH)₄·(H₂O)₂ (denoted 1) has been synthesized under mild solvothermal condition. The compound crystallizes in the chiral trigonal R32 (155) space group, with the following unit cell parameters: a = 11.172(3) Å, b = 11.172(3) Å, c = 21.282(10) Å; V = 2300.4(14) Å3; Z = 3. It has been characterized by single crystal X-ray analysis, element analysis, FTIR, PXRD, TG-DSC and Second-harmonic-generation response. Its structure contains [B₄O₅(OH)₄]2− polyanions, which are further linked by a rare [Na₄O₁₈] cluster to form a 3-D framework. Keywords Tetraborate Crystal structure Solvothermal