Design of New Camelina Oil-Based Hydrophilic Monomers for Novel Polymeric Materials
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- 作者：Brindusa Balanuca ; Raluca Stan…
- 关键词：Camelina oil ; Methacrylate ; Hydrophilic ; Bulk photo ; polymerization ; Emulsion photo ; polymerization
- 刊名：Journal of the American Oil Chemists' Society
- 出版年：2015
- 出版时间：June 2015
- 年：2015
- 卷：92
- 期：6
- 页码：881-891
- 全文大小：2,210 KB
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Raluca Stan (2)
Anamaria Hanganu (3)
Adriana Lungu (1)
Horia Iovu (1) (4)
1. Advanced Polymer Materials Group, Department of Bioresources and Polymer Science, University Politehnica of Bucharest, Bucharest, Romania
2. Department of Organic Chemistry “Costin Nenitescu- University Politehnica of Bucharest, Bucharest, Romania
3. Center of Organic Chemistry “Costin D. Nenitescu- Romanian Academy, Bucharest, Romania
4. Academy of Romanian Scientists, Bucharest, Romania - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Industrial Chemistry and Chemical Engineering
Analytical Chemistry
Chemistry
Biotechnology
Biomaterials
Agriculture - 出版者：Springer Berlin / Heidelberg
- ISSN：1558-9331
文摘
Triglyceride-based monomers represent a competitive alternative to petrochemical resources in the macromolecular compounds area. In the current study, several types of hydrophilic camelina oil (CO)-based monomers were synthesized using tunable experimental protocols that involve three different steps: first—conversion of the double bonds into epoxy rings, second—partial opening of the epoxy rings and methacrylic groups grafting and last—opening of the unreacted epoxy rings and hydrophilic units attaching. 1H-NMR, 13C-NMR and FTIR spectroscopy demonstrate the success of the CO functionalization with polymerizable and hydrophilic moieties—polyethylene glycol units—with different molecular weights, exhibiting self-emulsifiable properties. Several bulk and emulsion polymerization tests were performed for the synthesized monomers and their ability to build polymer networks using different photo-chemical procedures (using visible and UV radiations respectively) was demonstrated, without additional surfactants. FTIR spectroscopy indicates the polymerization success by the disappearance of the specific bands assigned to the double bonds from methacrylic groups and thermogravimetric analysis demonstrates that the emulsion polymerization leads to materials with an improved thermostability.