One-step strategy for synthesis of yolk–shell silica spheres using trisiloxane-tailed ionic liquids as a template
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- 作者：Zhiping Du (1) (2)
Enze Li (2)
Guojin Li (2)
Fangqin Cheng (1)
Guoyong Wang (2) - 刊名：Journal of Materials Science
- 出版年：2014
- 出版时间：July 2014
- 年：2014
- 卷：49
- 期：14
- 页码：4919-4926
- 全文大小：
- 参考文献：1. Liu J, Qiao SZ, Chen JS, Lou XWD, Xing X, Lu GQM (2011) Yolk/shell nanoparticles: new platforms for nanoreactors, drug delivery and lithium-ion batteries. Chem Commun 47:12578-2591 CrossRef
2. Liu J, Qiao SZ, Budi?Hartono S, Lu GQ (2010) Monodisperse yolk–shell nanoparticles with a hierarchical porous structure for delivery vehicles and nanoreactors. Angew Chem Int Ed 49:4981-985 CrossRef
3. Wu X-J, Xu D (2010) Soft template synthesis of yolk/silica shell particles. Adv Mater 22:1516-520 CrossRef
4. Lou XWD, Archer LA, Yang Z (2008) Hollow micro/nanostructures: synthesis and applications. Adv Mater 20:3987-019 CrossRef
5. Seh ZW, Li W, Cha JJ et al (2013) Sulphur–TiO2 yolk–shell nanoarchitecture with internal void space for long-cycle lithium–sulphur batteries. Nat Commun 4:1331 CrossRef
6. Liu J, Qiao SZ, Hu QH, Lu GQ (2011) Magnetic nanocomposites with mesoporous structures: synthesis and applications. Small 7:425-43 CrossRef
7. Park J, Song H (2011) Metal@Silica yolk–shell nanostructures as versatile bifunctional nanocatalysts. Nano Res 4:33-9 CrossRef
8. Cao A, Lu R, Veser G (2010) Stabilizing metal nanoparticles for heterogeneous catalysis. Phys Chem Chem Phys 12:13499-3510 CrossRef
9. Zhang T, Ge J, Hu Y, Zhang Q, Aloni S, Yin Y (2008) Formation of hollow silica colloids through a spontaneous dissolution–regrowth process. Angew Chem Int Ed 47:5806-811 CrossRef
10. Tan L, Chen D, Liu H, Tang F (2010) A silica nanorattle with a mesoporous shell: an ideal nanoreactor for the preparation of tunable gold cores. Adv Mater 22:4885-889 CrossRef
11. Lou XW, Yuan C, Rhoades E, Zhang Q, Archer LA (2006) Encapsulation and Ostwald ripening of Au and Au–Cl complex nanostructures in silica shells. Adv Funct Mater 16:1679-684 CrossRef
12. Wong YJ, Zhu L, Teo WS et al (2011) Revisiting the St?ber method: inhomogeneity in silica shells. J Am Chem Soc 133:11422-1425 CrossRef
13. Yang Y, Liu J, Li X, Liu X, Yang Q (2011) Organosilane-assisted transformation from core–shell to yolk–shell nanocomposites. Chem Mater 23:3676-684 CrossRef
14. Wu X-J, Xu D (2009) Formation of yolk/SiO2 shell structures using surfactant mixtures as template. J Am Chem Soc 131:2774-775 CrossRef
15. Liu B, Zeng HC (2005) Symmetric and asymmetric ostwald ripening in the fabrication of homogeneous core–shell semiconductors. Small 1:566-71 CrossRef
16. Cho EC, Camargo PHC, Xia Y (2010) Synthesis and characterization of noble-metal nanostructures containing gold nanorods in the center. Adv Mater 22:744-48 CrossRef
17. Yin Y, Rioux RM, Erdonmez CK, Hughes S, Somorjai GA, Alivisatos AP (2004) Formation of hollow nanocrystals through the nanoscale Kirkendall effect. Science 304:711-14 CrossRef
18. Arnal PM, Comotti M, Schüth F (2006) High-temperature-stable catalysts by hollow sphere encapsulation. Angew Chem Int Ed 45:8224-227 CrossRef
19. Ikeda S, Ishino S, Harada T et al (2006) Ligand-free platinum nanoparticles encapsulated in a hollow porous carbon shell as a highly active heterogeneous hydrogenation catalyst. Angew Chem Int Ed 45:7063-066 CrossRef
20. Li G, Shi Q, Yuan SJ, Neoh KG, Kang ET, Yang X (2010) Alternating silica/polymer multilayer hybrid microspheres templates for double-shelled polymer and inorganic hollow microstructures. Chem Mater 22:1309-317 CrossRef
21. Du Z, Li E, Cao Y, Li X, Wang G (2014) Synthesis of trisiloxane-tailed surface active ionic liquids and their aggregation behavior in aqueous solution. Colloid Surf A 441:744-51 CrossRef
22. Zhang LX, Li PC, Liu XH, Du LW, Wang EK (2007) The effect of template phase on the structures of as-synthesized silica nanoparticles with fragile didodecyldimethylammonium bromide vesicles as templates. Adv Mater 19:4279-283 CrossRef
23. Chen D, Li L, Tang F, Qi S (2009) Facile and scalable synthesis of tailored silica “nanorattle-structures. Adv Mater 21:3804-807 CrossRef
24. Liu J, Yang HQ, Kleitz F et al (2012) Yolk–shell hybrid materials with a periodic mesoporous organosilica shell: ideal nanoreactors for selective alcohol oxidation. Adv Funct Mater 22:591-99 CrossRef
25. Lee J, Park JC, Song H (2008) A nanoreactor framework of a Au@SiO2 yolk/shell structure for catalytic reduction of / p-nitrophenol. Adv Mater 20:1523-528 CrossRef
26. Chen Y, Chen H, Ma M et al (2011) Double mesoporous silica shelled spherical/ellipsoidal nanostructures: synthesis and hydrophilic/hydrophobic anticancer drug delivery. J Mater Chem 21:5290-298 CrossRef - 作者单位：Zhiping Du (1) (2)
Enze Li (2)
Guojin Li (2)
Fangqin Cheng (1)
Guoyong Wang (2)
1. Institute of Resources and Environment Engineering, Shanxi University, No. 92 Wucheng Road, Taiyuan, 030006, Shanxi, People’s Republic of China
2. China Research Institute of Daily Chemical Industry, No. 34 Wenyuan Road, Taiyuan, 030001, Shanxi, People’s Republic of China - ISSN：1573-4803
文摘
Yolk–shell silica spheres consisting of a core and an outer shell were prepared by a one-step method using a new class of eco-friendly templates, trisiloxane-tailed surface active ionic liquids. The effects of pH, calcination, and template concentration were investigated in detail. Our results showed that yolk–shell silica spheres could be obtained only in alkaline conditions when using trisiloxane-tailed ionic liquids as templates. The particle diameter, core diameter, dimension of void space, and shell thickness, which we measured by transmission electron microscopy and nitrogen adsorption–desorption techniques, could be tuned by precisely varying the template concentration. The organosilicon component of the ionic liquid template contributes to the reaction during the formation of yolk–shell nanostructures, which leads to a firm silica sphere skeleton resulting in essentially identical morphology and void structure before and after calcination. This investigation provides a convenient approach to fabricate yolk–shell silica spheres, which may expand the application of organosilicon ionic liquids in the field of nanomaterials and could be expected to generate tailor-made yolk–shell silica with functionality in both the core and shell.