Heterogeneous Alkane Reactions over Nanoporous Catalysts

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• 作者：Talib M. N. Albayati (1)
  Sophie E. Wilkinson (2)
  Arthur A. Garforth (2)
  Aidan M. Doyle (3)
  
• 关键词：$$n$$ n ; Heptane hydroisomerisation ; Zeolites ; Mesoporous silica ; SBA ; 15
• 刊名：Transport in Porous Media
• 出版年：2014
• 出版时间：September 2014
• 年：2014
• 卷：104
• 期：2
• 页码：315-333
• 全文大小：1,751 KB
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• 作者单位：Talib M. N. Albayati (1)
  Sophie E. Wilkinson (2)
  Arthur A. Garforth (2)
  Aidan M. Doyle (3)
  
  1. Department of Chemical Engineering, University of Technology, 52 Alsinaa St., PO Box 35010, Baghdad, Iraq
  2. School of Chemical Engineering and Analytical Science, University of Manchester, Oxford Road, Manchester, M13 9PL, UK
  3. Division of Chemistry and Environmental Science, Manchester Metropolitan University, Chester St., Manchester, M1 5GD, UK
  
• ISSN：1573-1634

文摘

Pt-USY-712 (Si/Al = 6) and three SBA-15 catalysts (metal-loaded with 1 wt% Pt, 1 wt% Ni or 0.5 wt% Pt and 0.5 wt% Ni) were prepared and characterised using scanning electron microscopy (SEM), X-ray diffraction (XRD), N \(_{2}\) adsorption porosimetry / BET and transmission electron microscopy (TEM). The catalysts were then tested in the hydroisomerisation and hydrocracking of \(n\) -heptane using a micro-reactor at atmospheric pressure, and the products were analysed by GC-FID. Reaction temperatures ranged from 250-span class="a-plus-plus inline-equation id-i-eq3"> \(400\,\,^{\circ }\hbox {C}\) while the W/F values of \(n\hbox {-C}_{7}\) varied from 224.70-50.57 kg \(\hbox {mol}^{-1}\) . The coke content of each catalyst was measured using thermo gravimetric analysis (TGA). The catalytic activity was highest on Pt-USY-712 at the lowest reaction temperatures due to (a) the presence of strong Br?nsted acids sites on the zeolite and (b) the smaller and more highly dispersed metal clusters on Pt-USY-712, relative to Pt-SBA-15. The activity was higher on the bimetallic Pt/Ni-SBA-15 than on mono-metallic Pt-SBA-15 as the co-impregnation of Ni with Pt enhanced the distribution of the metal clusters on the catalyst and resulted in improved surface area for reaction. The Pt-SBA-15 and Pt/Ni-SBA-15 catalysts both had the lowest and approximately equal coke percentages with 0.116 and 0.119 wt%, respectively.