Preparation of monodisperse poly(styrene-co-divinylbenzene) microspheres by vibration dispersion method

详细信息    查看全文

• 作者：Ye Wang ; Guobing Li ; Song Chen ; Rongshuang Si…
• 关键词：Monodisperse ; Poly(Styrene ; co ; divinylbenzene) ; Vibration Dispersion Method ; Droplets ; Drop Size
• 刊名：Korean Journal of Chemical Engineering
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：33
• 期：1
• 页码：312-318
• 全文大小：1,584 KB
• 参考文献：1.Y. Yuan and X. C. Xiao, Polym. Sci. Ser. B, 53, 431 (2011).CrossRef
  2.M. Rounds, W. Rounds and F. Regnier, J. Chromatogr. A, 397, 25 (1987).CrossRef
  3.X. Cheng, R. Liu and Y. He, Eur. J. Pharm. Biopharm., 76, 336 (2010).CrossRef
  4.X. J. Dai, Y. He, Y. M. Wei and B. L. Gong, J. Sep. Sci., 34, 3115 (2011).CrossRef
  5.M. Omer-Mizrahi and S. Margel, Polymer, 51, 1222 (2010).CrossRef
  6.E. Unsal, A. Durdu, B. Elmas, M. Tuncel and A. Tuncel, Anal. Bioanal. Chem., 383, 930 (2005).CrossRef
  7.S. Li, J. Cheng, K. Wang and Z. R. Yang, Chem. Res. Chin. Univ., 24, 378 (2008).CrossRef
  8.S. Kawaguchi and K. Ito, Polymer particles, Springer-Verlag Berlin, Berlin (2005).
  9.G. H. Ma, H. Sone and S. Omi, Macromolecules, 37, 2954 (2004).CrossRef
  10.R. F. Meyer, W. B. Rogers, M. T. McClendon and J. C. Crocker, Langmuir, 26, 14479 (2010).CrossRef
  11.A. Singh and D. Lal, J. Appl. Polym. Sci., 100, 2323 (2006).CrossRef
  12.E. M. Lee, H. W. Lee, J. H. Park, Y. A. Han, B. C. Ji, W. T. Oh, Y. L. Deng and J. H. Yeum, Colloid Polym. Sci., 286, 1379 (2008).CrossRef
  13.T. H. Sun, L. K. Cao and J. P. Jia, Chromatographia, 61, 173 (2005).CrossRef
  14.H. Qu, F. Gong, G. Ma and Z. Su, J. Appl. Polym. Sci., 105, 1632 (2007).CrossRef
  15.P. Yu, Q. L. Sun, J. M. Pan, Z. J. Tan, J. D. Dai, Y. S. Yan and F. Cheng, Adsorpt. Sci. Technol., 31, 641 (2013).CrossRef
  16.C. Chen, Z. G. Zhu, W. H. Shih, Q. Q. Ge, M. J. Liu and X. R. Zhu, J. Nanosci. Nanotechnol., 15, 3239 (2015).CrossRef
  17.G. H. Ma, C. J. An, H. Yuyama, Z. G. Su and S. Omi, J. Appl. Polym. Sci., 89, 163 (2003).CrossRef
  18.G. H. Ma, J. Fujiwara, Z. G. Su and S. Omi, J. Polym. Sci. Chem., 41, 2588 (2003).CrossRef
  19.C. L. Yang, Y. P. Guan, J. M. Xing, J. G. Liu, G. B. Shan, Z. T. An and H. Z. Liu, AIChE J., 51, 2011 (2005).CrossRef
  20.K. Ogino, H. Sato, K. Tsuchiya, H. Suzuki and S. Moriguchi, J. Chromatogr. A, 699, 59 (1995).CrossRef
  21.C. H. Kim, J. G. Park, J. W. Kim and J. B. Jun, Korean J. Chem. Eng., 20, 399 (2003).CrossRef
  22.X. X. Zhu, J. H. Zhang, M. Gauthier, J. T. Luo, F. S. Meng and F. Brisse, J. Comb. Chem., 8, 79 (2006).CrossRef
  23.U. C. Sung, C. N. Yoon and S. G. Kim, Korean J. Chem. Eng., 14, 15 (1997).CrossRef
  24.C. X. Zhao and A. P. J. Middelberg, Chem. Eng. Sci., 66, 1394 (2011).CrossRef
  25.L. L. Lazarus, C. T. Riche, B. C. Marin, M. Gupta, N. Malmstadt and R. L. Brutchey, ACS Appl. Mater. Interfaces, 4, 3077 (2012).CrossRef
  26.C. Dumouchel, Exp. Fluids, 45, 371 (2008).CrossRef
  27.M. J. McCarthy and N. A. Molloy, Chem. Eng. J., 7, 1 (1974).CrossRef
  28.T. Sakai, N. Koshino, J. Chem. Eng. Japan, 13, 267 (1980).
  29.A. Paul, Hass, Ind. Eng. Chem. Res., 31, 959 (1992).CrossRef
  30.S. Q. Armster, J. P. Delplanque, W. H. L. Lai and E. J. Lavernia, Metall. Mater. Trans. B-Proc. Metall. Mater. Proc. Sci., 31, 1333 (2000).CrossRef
  
• 作者单位：Ye Wang (1)
  Guobing Li (1)
  Song Chen (1)
  Rongshuang Si (1)
  Jiangyang Fan (1)
  
  1. School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, P. R. China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Industrial Chemistry and Chemical Engineering
  Catalysis
  Materials Science
  Biotechnology
  
• 出版者：Springer New York
• ISSN：1975-7220

文摘

Monodisperse micron-size poly(styrene-co-divinylbenzene) (PST-DVB) microspheres were successfully prepared by vibration dispersion. A vibrator was used to generate a controlled vibration to jet from a single nozzle of 200 µm to produce uniform droplets. The effects of variations in selected process parameters upon the droplets formation and the diameter of the microspheres were investigated. It was demonstrated that changes in the velocity of oil phase, drive frequency and destabilization amplitude have significant effects on the formation of uniform droplets and the average diameter of the microspheres. Rational polynomial regression equations of the above parameters were established. Based on these equations, we could calculate the operation conditions to produce uniform droplets with the desirable diameter.