Preparation of Ferrocene-Based Coordination Polymer Microspheres and Their Application in Hydrogen Storage
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- 作者：Yubiao Sun (1)
Haojie Yu (1)
Li Wang (1)
Yulai Zhao (1)
Wenbin Ding (1)
Jing Ji (1)
Yongsheng Chen (1)
Fujie Ren (1)
Zhifei Tian (1)
Liang Huang (1)
Pengfei Ren (1)
Rongbai Tong (1) - 关键词：Ferrocene ; based metalloligand ; Coordination polymer microsphere ; Growth mechanism ; Hydrogen storage ; Adsorption enthalpy
- 刊名：Journal of Inorganic and Organometallic Polymers and Materials
- 出版年：2014
- 出版时间：May 2014
- 年：2014
- 卷：24
- 期：3
- 页码：491-500
- 全文大小：1,579 KB
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Haojie Yu (1)
Li Wang (1)
Yulai Zhao (1)
Wenbin Ding (1)
Jing Ji (1)
Yongsheng Chen (1)
Fujie Ren (1)
Zhifei Tian (1)
Liang Huang (1)
Pengfei Ren (1)
Rongbai Tong (1)
1. State Key Laboratory of Chemical Engineering, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, People’s Republic of China - ISSN：1574-1451
文摘
In this article, a functional ferrocene-based metalloligand has been synthesized and used as the building block to assemble novel coordination polymer microspheres. Specifically, this metalloligand was coordinated with two different types of metal ions (Co2+ and Mn2+) to fabricate two different but isostructural microspheres under solvothermal conditions. To deepen our understanding of the formation process of the coordination polymer microspheres, a growth mechanism has been proposed based on the morphology change of these spheres throughout the whole reaction process. Furthermore, the prepared multi disperse microspheres, in the form of hollow spheres with high thermostability, can be applied to store hydrogen for their promising hydrogen uptake capacity (1.84wt% for CPM-1 and 1.00 wt% for CPM-2 at 163?K under 5?MPa). Moreover, the different adsorption enthalpies of these two materials that relevant to the varied hydrogen uptake capacity have been calculated, compared and explained.