Studies on the potassium–nickel hexacyanoferrate/ethanolamine/silica ion exchanger for 60Co removal from spent fuel storage basins and the primary water circuit of nuclear reactors

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• 作者：Dagmara Chmielewska ; Lena Stachurska
• 关键词：Potassium–nickel hexacyanoferrate ; Ethanolamine ; Silica ; Nanocomposite ; Radiocobalt
• 刊名：Journal of Radioanalytical and Nuclear Chemistry
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：307
• 期：2
• 页码：1295-1301
• 全文大小：670 KB
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• 作者单位：Dagmara Chmielewska (1)
  Lena Stachurska (2)
  
  1. Institute of Nuclear Chemistry and Technology, Dorodna 16, 03-195, Warsaw, Poland
  2. Faculty of Chemical and Process Engineering, Warsaw University of Technology, Warynskiego 1, 00-645, Warsaw, Poland
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Nuclear Chemistry
  Physical Chemistry
  Nuclear Physics, Heavy Ions and Hadrons
  Diagnostic Radiology
  Inorganic Chemistry
  
• 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
• ISSN：1588-2780

文摘

Additional modification of the potassium–nickel hexacyanoferrate/silica composite with ethanolamine lead to synthesis of a nanocomposite ion exchanger, characterized by a high specific area and high selectivity for Co2+ ions. Presence of high amounts of inactive metal ions such as Na+, K+, Ca2+ and Mg2+ in CoCl₂ solutions in seawater leads to a decrease of the distribution coefficient, although even in such conditions the ion exchanger is highly selective for the cobalt(II) ions. An additional advantage of the synthesized ion exchanger is high thermal stability and resistance to γ radiation. Keywords Potassium–nickel hexacyanoferrate Ethanolamine Silica Nanocomposite Radiocobalt