Statistical analysis of water discharging from rocks of different origin: a case study from Turkey
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- 作者：Tülay Ekemen Keskin ; Fikret Kaçaroğlu ; Taner Ersöz…
- 关键词：Hydrogeochemistry statistical analyses ; Water contamination ; Sivas ; Karabük ; Bartın
- 刊名：Environmental Earth Sciences
- 出版年：2016
- 出版时间：February 2016
- 年：2016
- 卷：75
- 期：4
- 全文大小：10,480 KB
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Fikret Kaçaroğlu (2)
Taner Ersöz (3)
Muharrem Düğenci (4)
1. Environmental Engineering Department, Karabük University, 78050, Karabuk, Turkey
2. Geology Engineering Department, Muğla Sıtkı KOÇMAN University, 48000, Muğla, Turkey
3. Actuarial and Risk Management Department, Karabük University, 78050, Karabuk, Turkey
4. Industrial Engineering Department, Karabük University, 78050, Karabuk, Turkey - 刊物类别：Earth and Environmental Science
- 刊物主题：None Assigned
- 出版者：Springer Berlin Heidelberg
- ISSN：1866-6299
文摘
The present study was conducted in Sivas, Karabük and Bartın regions of Turkey, which have rocks of different origins, agricultural and mining activities. Correlation, principal components, hierarchical cluster and multidimensional scaling analyses were applied to determine the processes controlling the chemical composition of groundwater. The results show that dissolution-weathering process, agricultural activities, oxidation processes of sulfide minerals, mining activities, coal levels, alteration of volcanics and progressive silicate hydrolysis effects the physicochemical properties of groundwater in the study areas. Principal components and multidimensional scaling analyses provided excellent visual representations of the grouping of the waters. The significant variables in the first factor are SO4, Mn, Fe, Al, and pH. The factor represents the groundwater reached by these elements via the dissolution and oxidation processes of sulfide minerals (especially pyrite). Ca, EC, and HCO3 are generally grouped under the second factor representing the dissolution of carbonate rocks. The third factor represented by Na, CO3, and pH is mostly related to alteration of volcanics, progressive silicate hydrolysis and dissolution, and probably ion exchange between Ca and Na. The fourth factor of NO3 and Cl is strongly influenced by agricultural activity. The measurement, analyses and evaluation results showed that the groundwater contamination is caused by (1) NO3 in waters discharging from clastic rocks in areas where intensive agricultural activities are conducted; (2) Al, Fe, Mn, and SO4 ions in water emerging from volcanics containing Pb–Zn–Cu ore deposits; and (3) Al, Fe, and Mn in water issuing from coal levels and altered volcanics. Some of these waters are used by adjacent towns for drinking, domestic, and irrigation purposes. Keywords Hydrogeochemistry statistical analyses Water contamination Sivas Karabük Bartın