Remarkable catalytic performance of H–Fe–FSM-16, synthesized by use of a microwave hydrothermal process, in the acetylation of 1,2-dimethoxybenzene

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• 作者：A. Baradji ; K. Bachari
• 关键词：Iron ; modified folded ; sheet mesoporous materials ; Acidity ; 1 ; 2 ; Dimethoxybenzene ; Acetylation ; Acetic anhydride
• 刊名：Research on Chemical Intermediates
• 出版年：2015
• 出版时间：March 2015
• 年：2015
• 卷：41
• 期：3
• 页码：1473-1483
• 全文大小：233 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1568-5675

文摘

A series of acidic, iron-modified, folded-sheet mesoporous materials with different Si-to-Fe ratios has been investigated as catalysts for liquid phase acetylation of 1,2-dimethoxybenzene with acetic anhydride. The catalysts were synthesized by use of a microwave–hydrothermal (M–H) process and characterized by N2 adsorption measurements, X-ray diffraction, electron spin resonance (ESR), M?ssbauer spectroscopy, and temperature-programmed desorption (TPD) of pyridine. The catalyst H–Fe–FSM-16 (M–H) (10) resulted in the best performance in acid-catalyzed acetylation of 1,2-dimethoxybenzene with acetic anhydride as acylating agent. The kinetics of acetylation of 1,2-dimethoxybenzene over these catalysts was also investigated.