Quaternary Pt2Ru1Fe1M1/C (M=Ni, Mo, or W) catalysts for methanol electro-oxidation reaction

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• 作者：Min Ku Jeon (1)
  Ki Rak Lee (1)
  Hyung Joon Jeon (2)
  Paul J. McGinn (3)
  Kweon Ho Kang (1)
  Geun Il Park (1)
  
  1. Nuclear Fuel Cycle Process Development Division ; Korea Atomic Energy Research Institute ; Daedeok-daero 989-111 ; Yuseong-gu ; Daejeon ; 305-353 ; Korea
  2. Institute for Integrated Cell-Material Sciences (iCeMS) ; Kyoto University ; Katsura ; Nishikyo-ku ; Kyoto ; 615-8510 ; Japan
  3. Department of Chemical and Biomolecular Engineering ; University of Notre Dame ; Notre Dame ; IN ; 46556 ; USA
  
• 关键词：Methanol Electro ; oxidation Reaction ; Direct Methanol Fuel Cell ; Electrocatalyst ; X ; ray Photoelectron Spectroscopy ; CO Electro ; oxidation
• 刊名：Korean Journal of Chemical Engineering
• 出版年：2015
• 出版时间：February 2015
• 年：2015
• 卷：32
• 期：2
• 页码：206-215
• 全文大小：1,607 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Industrial Chemistry and Chemical Engineering
  Catalysis
  Materials Science
  Biotechnology
  
• 出版者：Springer New York
• ISSN：1975-7220

文摘

Quaternary Pt2Ru1Fe1Ni1/C (M=Ni, Mo, or W) catalysts were investigated for the methanol electro-oxidation reaction (MOR). Electrocatalytic activities of the quaternary catalysts for CO electro-oxidation were studied via CO stripping experiments, and the Pt2Ru1Fe1Ni1/C and Pt2Ru1Fe1W1/C catalysts exhibited lowered on-set potential compared to that of a commercial PtRu/C catalyst. MOR activities of the quaternary catalysts were determined by linear sweep voltammetry (LSV) experiments, and the Pt2Ru1Fe1Ni1/C catalyst outperformed the commercial PtRu/C catalyst by 170 and 150% for the mass and specific activities, respectively. X-ray photoelectron spectroscopy (XPS) was employed to analyze surface oxidation states of constituent atoms, and it was identified that the structure of the synthesized catalysts are close to a nano-composite of Pt and constituent metal hydroxides and oxides. In addition, the XPS results suggested that the bi-functional mechanism accounts for the improved performance of the Pt2Ru1Fe1Ni1/C and Pt2Ru1 Fe1W1/C catalysts.